Optode sensing membranes employing decyl methacrylate cross-linked with 1,6-hexanediol dimethacrylate as the polymer support were fabricated by a direct microspotting method on several surfaces. Photopolymerization was used to attach the microspots to the substrate. Using this method, diameters in the micrometer domain were obtained. Silanized glass, poly(methyl methacrylate) (PMMA), polycarbonate, and poly(dimethylsiloxane) were tested as possible substrates. Both polypropylene tips and the steel tips of drafting pens were used for spotting. It was determined that both silanized glass and PMMA gave working optodes, but the ones on PMMA did not fit the theoretical model. Diameters of 994 +/- 80 and 1279 +/- 85 microm were obtained on silanized glass and PMMA, respectively, using the polypropylene tips for spotting. Different size optodes were fabricated using 0.35- and 0.50-mm steel drafting pen tips. The 0.35-mm tips produced diameters of 895 +/- 26 and 688 +/- 54 microm on silanized glass and PMMA, respectively, and the 0.50-mm tips produced diameters of 1274 +/- 94 microm on silanized glass and 839 +/- 28 microm on PMMA. Thus, the microspot size can be controlled based on the hydrophobicity of the surface and the size of the tip used for spotting. Calibration plots of potassium optode microspots indicated that miniaturization does not alter response characteristics, such as selectivity, response time, and dynamic range, of the optodes.
As water scarcity becomes more prevalent across the world, the risk to industry rises. There is a growing need for a practical tool that can map water use and effectively assess water risks for industries, especially global companies and organizations with operations and suppliers in numerous countries.The Dow Chemical Company (Dow) participated in the development of the World Business Council for Sustainable Development (WBCSD) Global Water Tool. Dow used the metrics and mapping results generated by the tool to review and communicate corporate risks with internal stakeholders.The WBCSD Global Water Tool has given Dow a unique and valuable perspective on the water use and relative corporate risks in their global operations. The Global Reporting Initiative metrics were especially useful for business stakeholders to frame the relative risks that exposure presents at the various production facilities.
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