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The GEOTRACES Intermediate Data Product 2014 (IDP2014) is the first publicly available data product of the international GEOTRACES programme, and contains data measured and quality controlled before the end of 2013. It consists of two parts: (1) a compilation of digital data for more than 200 trace elements and isotopes (TEls) as well as classical hydrographic parameters, and (2) the eGEOTRACES Electronic Atlas providing a strongly inter-linked on-line atlas including more than 300 section plots and 90 animated 3D scenes. The IDP2014 covers the Atlantic, Arctic, and Indian oceans, exhibiting highest data density in the Atlantic. The TEI data in the IDP2014 are quality controlled by careful assessment of intercalibration results and multi-laboratory data comparisons at cross-over stations. The digital data are provided in several formats, including ASCII spreadsheet, Excel spreadsheet, netCDF, and Ocean Data View collection. In addition to the actual data values the IDP2014 also contains data quality flags and 1-sigma data error values where available. Quality flags and error values are useful for data filtering. Metadata about data originators, analytical methods and original publications related to the data are linked to the data in an easily accessible way. The eGEOTRACES Electronic Atlas is the visual representation of the IDP2014 data providing section plots and a new kind of animated 3D scenes. The basin-wide 3D scenes allow for viewing of data from many cruises at the same time, thereby providing quick overviews of large-scale tracer distributions. In addition, the 3D scenes provide geographical and bathymetric context that is crucial for the interpretation and assessment of observed tracer plumes, as well as for making inferences about controlling processes. (C) 2015 The Authors. Published by Elsevier B.V

Helium concentrations and isotopic ratios have been measured in a suite of basaltic olivines from the Hawaii Scientific Drilling Project (HSDP) core at Hilo, Hawaii, which allows a characterization of the temporal helium isotopic evolution of Mauna Kea volcano. Typically more than 85% of the helium within the olivines is released by crushing, which demonstrates that helium is dominantly contained within the melt inclusions, and strongly suggests that helium behaves as an incompatible element during silicate melting. Lavas from the base of the Mauna Loa section of the core (240–270 m depth) have 3He/4He ratios between 13.9 and 15.8 times atmospheric (Ra). These values, when combined with Sr and Nd isotopic data, correspond to those previously found in subaerial Mauna Loa lavas that are greater than 30 ka in age, place a minimum age of 30 ka for the top of the Mauna Kea section, and are consistent with radiocarbon chronology. The upper part of the Mauna Kea lava section (290–620 m) has 3He/4He ratios of 7.0 to 6.8 Ra, similar to most mid‐ocean ridge basalts and is thought to represent the normal asthenospheric mantle signature. Between 620 and 670 m depth there is a transition to higher values, with 3He/4He ratios between 10.2 and 12.5 Ra at depths greater than 670 m, suggesting a greater contribution of undegassed plume material to the older Mauna Kea tholeiites. The correlations between He, Nd, and Pb isotope ratios demonstrate that the helium isotopic variations are related to mixing of source materials rather than shallow contamination effects (i.e., via addition of radiogenic 4He). The transition from high to low 3He/4He ratios occurs within the tholeiitic shield of Mauna Kea. The highest 3He/4He ratios in the Mauna Kea lavas (up to 12.5 Ra) are significantly lower than the values found in the shield tholeiites of the adjacent volcanoes (Loihi Seamount, Mauna Loa, and Kilauea); this relates to a smaller hot spot contribution to the Mauna Kea lavas. The temporal helium isotopic evolution of Hawaiian shield volcanos (with highest 3He/4He ratios found in the oldest lavas) and the inter‐volcano variations (with the Mauna Kea shield having the lowest 3He/4He ratios on the island) are attributed to movement of the Pacific plate over a radially zoned hot spot.

Concentrations of elemental carbon (EC) were measured in a 150 yr sediment record collected from Lake Chaohu in Anhui Province, eastern China, using three different thermal analytical methods: IMPROVE_A thermal optical reflectance (TOR), STN_thermal optical transmittance (TOT), and chemothermal oxidation (CTO). Distribution patterns for EC concentrations are different among the three methods, most likely due to the operational definition of EC and different temperature treatments prescribed for each method. However, similar profiles were found for high-temperature EC fractions among different methods. Historical soot(TOR) (high-temperature EC fractions measured by the IMPROVE_A TOR method) from Lake Chaohu exhibited stable low concentrations prior to the late 1970s and a sharp increase thereafter, corresponding well with the rapid industrialization of China in the last three decades. This may suggest that high-temperature thermal protocols are suitable for differentiating between soot and other carbon fractions. A similar soot(TOR) record was also obtained from Lake Taihu (~200 km away), suggesting a regional source of soot. The ratio of char(TOR) (low-temperature EC fraction measured by the IMPROVE_A TOR method, after correction for pyrolysis) to soot(TOR) in Lake Chaohu shows an overall decreasing trend, consistent with gradual changes in fuel use from wood burning to increasing fossil fuel combustions. Average higher char(TOR)/soot(TOR) was observed in Lake Taihu than in Lake Chaohu in the past 150 years, consistent with the longer and more extensive industrialization around the Taihu region.