Spatial distributions of soil properties at the field and watershed scale may affect yield potential, hydrologic responses, and transport of herbicides and NO−3 to surface or groundwater. Our research describes field‐scale distributions and spatial trends for 28 different soil parameters at two sites within a watershed in central Iowa. Two of 27 parameters measured at one site and 10 of 14 parameters measured at the second site were normally distributed. Spatial variability was investigated using semivariograms and the ratio of nugget to total semivariance, expressed as a percentage, was used to classify spatial dependence. A ratio of <25% indicated strong spatial dependence, between 25 and 75% indicated moderate spatial dependence, and >75% indicated weak spatial dependence. Twelve parameters at Site one, including organic C, total N, pH, and macroaggregation, and four parameters at Site two, including organic C and total N, were strongly spatially dependent. Six parameters at Site one, including biomass C and N, bulk density, and denitrification, and 9 parameters at Site two, including biomass C and N and bulk density, were moderately spatially dependent. Three parameters at Site one, including NO−3 N and ergosterol, and one parameter at Site two, mineral‐associated N, were weakly spatially dependent. Distributions of exchangeable Ca and Mg at Site one were not spatially dependent. Spatial distributions for some soil properties were similar for both field sites. We will be able to exploit these similarities to improve our ability to extrapolate information taken from one field to other fields within similar landscapes.

A significant portion of the NO3 from agricultural fields that contaminates surface waters in the Midwest Corn Belt is transported to streams or rivers by subsurface drainage systems or "tiles." Previous research has shown that N fertilizer management alone is not sufficient for reducing NO3 concentrations in subsurface drainage to acceptable levels; therefore, additional approaches need to be devised. We compared two cropping system modifications for NO3 concentration and load in subsurface drainage water for a no-till corn (Zea mays L.)-soybean (Glycine max [L.] Merr.) management system. In one treatment, eastern gamagrass (Tripsacum dactyloides L.) was grown in permanent 3.05-m-wide strips above the tiles. For the second treatment, a rye (Secale cereale L.) winter cover crop was seeded over the entire plot area each year near harvest and chemically killed before planting the following spring. Twelve 30.5x42.7-m subsurface-drained field plots were established in 1999 with an automated system for measuring tile flow and collecting flow-weighted samples. Both treatments and a control were initiated in 2000 and replicated four times. Full establishment of both treatments did not occur until fall 2001 because of dry conditions. Treatment comparisons were conducted from 2002 through 2005. The rye cover crop treatment significantly reduced subsurface drainage water flow-weighted NO3 concentrations and NO3 loads in all 4 yr. The rye cover crop treatment did not significantly reduce cumulative annual drainage. Averaged over 4 yr, the rye cover crop reduced flow-weighted NO3 concentrations by 59% and loads by 61%. The gamagrass strips did not significantly reduce cumulative drainage, the average annual flow-weighted NO3 concentrations, or cumulative NO3 loads averaged over the 4 yr. Rye winter cover crops grown after corn and soybean have the potential to reduce the NO3 concentrations and loads delivered to surface waters by subsurface drainage systems.

Nonpoint source contamination of surface and groundwater resources with nitrate-N (NO3-N) has been linked to agriculture across the midwestern USA. A 4-yr study was conducted to assess the extent of NO3-N leaching in a central Iowa field. Water flow rate was monitored continuously and data were stored on an internal datalogger. Water samples for chemical analysis were collected weekly provided there was sufficient flow. Twelve soil cores were collected in spring, early summer, midsummer , and after harvest for each of the 4 yr. Nitrate-N concentrations in shallow groundwater exhibited temporal trends and were higher under Clarion soil than under Okoboji or Canisteo soil. Denitrification rates were two times higher in Okoboji surface soil than in Clarion surface soil and the highest denitrificafion potential among subsurface sediments was observed for deep unoxidized loess. Soil profile NO~-N concentrations decreased with depth and were the same below 30 cm for fertilized corn (Zea mays L.) and soybean (Glycine max L. Merr.). Nitrate-N concentrations in subsurface drainage water exceeded 10 mg L-1 for 12 mo and were between 6 and 9 mg L-1 for 32 mo during the 4-yr study. The temporal pattern of NO3-N concentrations in subsurface drainage water was not related to the timing of fertilizer N application or the amount of fertilizer N applied. Total NO~-N losses to subsurface drains were greatest in 1993 (51.3 kg ha-1) and least in 1994 (4.9 kg ha-l). Most of the subsurface drainage water NO~-N was lost when crop plants were not present (November-May), except in 1993. Our results indicate that NO~-N losses to subsurface drainage water occur primarily as a result of asynchronous production and uptake of NO~-N in the soil and the presence of large quantifies of potentially mineralizable N in the soil organic matter. N ONPOINT SOURCE contamination of surface-and groundwater with NO3-N has been linked to agricultural production in the midwestern USA. This is especially true for surface waters in the upper Midwest due to extensive subsurface draining of the highly productive but poorly drained soils found in this region (Gast et al., 1978). However, the extent to which agriculture contributes to water-quality deterioration is not fully known. In some geographic regions, surface-water NO3-N concentrations in excess of the 10 mg L-1 drinking water standard frequently have been reported (Hallberg, 1986). Keeney and DeLuca (1993) found that NO3-N concentrations in Des Moines river water in central Iowa were above 10 mg L-1 for an average of 14 d per year, generally in the spring. Subsurface drainage water NO3-N concentrations exhibit yearly and seasonal variability (Kladivko et al., 1991). Nitrogen flux to subsurface drains appears to be primarilly a function of precipitation amounts and distribution, and is only slightly affected by crop N up

Nonpoint‐source pollution has been linked to agricultural practices; however, there is a need for quantitative information describing the effect of specific farming practices on ground and surface water quality. Lack of information at the watershed scale limits our ability to make decisions about the effect of potential changes in either farming practices or landscape management that would enhance water quality. A multidisciplinary study was designed to evaluate the effect of farming practices on subsurface drainage, surface runoff, stream discharge, groundwater, volatilization, and soil processes that influence water quality. Walnut Creek watershed is a 5130‐ha intensively cropped area in central Iowa on the Des Moines Lobe landform region. Soils within the watershed are in the Clarion‐Nicollet‐Webster (Typic Hapludoll‐Aquic Hapludoll‐Typic Haplaquoll) soil association, and the underlying surficial material is glacial till. Land use is predominantly corn (Zea mays L.)‐soybean [Glycine max (L.) Merr.] rotation. Fertilizer use, herbicide application, tillage practices, and crop selection were obtained through surveys of each field operator. Atrazine [6‐chloro‐N‐ethyl‐N′‐(1‐methylethyl)‐1,3,5‐triazine‐2,4‐diamine], cyanazine [2‐[[4‐chloro‐6‐(ethylamino)‐1,3,5‐triazin‐2‐yl]amino]‐2‐methylpropanenitrile], EPTC [S‐ethyl dipropyl carbamothioatel, and metolachlor [2‐chloro‐N‐(2‐ethyl‐6‐methyiphenyl)‐N‐(2‐methoxy‐1‐methylethyl)acetamide] are the primary herbicides used within the watershed at rates similar to those for the state. Nitrogen fertilizer was applied as anhydrous ammonia on 60% of the corn fields at an average rate of 153 kg ha−1 for the 1991–1994 period, but the frequency of corn fields receiving <112 kg ha−1 has increased.

Nitrate in water removed from fields by subsurface drain ('tile') systems is often at concentrations exceeding the 10 mg N L(-1) maximum contaminant level (MCL) set by the USEPA for drinking water and has been implicated in contributing to the hypoxia problem within the northern Gulf of Mexico. Because previous research shows that N fertilizer management alone is not sufficient for reducing NO(3) concentrations in subsurface drainage below the MCL, additional approaches are needed. In this field study, we compared the NO(3) losses in tile drainage from a conventional drainage system (CN) consisting of a free-flowing pipe installed 1.2 m below the soil surface to losses in tile drainage from two alternative drainage designs. The alternative treatments were a deep tile (DT), where the tile drain was installed 0.6 m deeper than the conventional tile depth, but with the outlet maintained at 1.2 m, and a denitrification wall (DW), where trenches excavated parallel to the tile and filled with woodchips serve as additional carbon sources to increase denitrification. Four replicate 30.5- by 42.7-m field plots were installed for each treatment in 1999 and a corn-soybean rotation initiated in 2000. Over 5 yr (2001-2005) the tile flow from the DW treatment had annual average NO(3) concentrations significantly lower than the CN treatment (8.8 vs. 22.1 mg N L(-1)). This represented an annual reduction in NO(3) mass loss of 29 kg N ha(-1) or a 55% reduction in nitrate mass lost in tile drainage for the DW treatment. The DT treatment did not consistently lower NO(3) concentrations, nor reduce the annual NO(3) mass loss in drainage. The DT treatment did exhibit lower NO(3) concentrations in tile drainage than the CN treatment during late summer when tile flow rates were minimal. There was no difference in crop yields for any of the treatments. Thus, denitrification walls are able to substantially reduce NO(3) concentrations in tile drainage for at least 5 yr.