The wood biomass obtained from four tree species: spruce, beech, willow and alder was studied. Sawdust obtained by sawing of wood was dried in a convective dryer at 80°C, without drying-agent flow. The measurements taken with oven-drying method covered determination of initial moisture and its detailed changes during entire drying process. Both DSC curves and spectral data from infrared spectra registered in the classic MIR range were also used to monitor change in water content in studied samples within entire drying process. Results obtained suggest that the DSC curves can be efficiently used as a discriminant to distinguish dry and wet biomass samples, as significant differences within courses of specific DSC curves of woody biomass before and after drying process occurred. Calorimetrically measured values of enthalpy of evaporation of water and water content in studied biomass samples were directly proportional to high determination coefficient, i.e. 0.9653. Statistical analysis proved quantitative directly proportional correlation between content of water measured with oven-drying method and IR spectral data of studied samples.
Hydrogen is increasingly considered as an environmentally friendly energy source as it stores a large amount of chemical energy per unit mass (142 MJ·kg−1) that can be released without the emission of combustion by-products. The presented research is based on simulation modeling of biohydrogen production projects from agricultural waste. Based on the probability theory and mathematical statistics, the models of the variable market value of biohydrogen and natural gas are substantiated. The results of the research indicate that in 2019, projects regarding the production of biohydrogen from agricultural raw materials were mostly unprofitable for the investors. However, starting in 2030, the forecasted return on investment in biohydrogen production projects from agricultural raw materials indicates that such projects will be profitable for investors, and the number and scale of such projects will significantly increase worldwide.
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