One of the five largest mass extinctions of the past 600 million years occurred at the boundary of the Triassic and Jurassic periods, 201.6 million years ago. The loss of marine biodiversity at the time has been linked to extreme greenhouse warming, triggered by the release of carbon dioxide from flood basalt volcanism in the central Atlantic Ocean. In contrast, the biotic turnover in terrestrial ecosystems is not well understood, and cannot be readily reconciled with the effects of massive volcanism. Here we present pollen, spore and geochemical analyses across the Triassic/Jurassic boundary from three drill cores from Germany and Sweden. We show that gymnosperm forests in northwest Europe were transiently replaced by fern and fern-associated vegetation, a pioneer assemblage commonly found in disturbed ecosystems. The Triassic/Jurassic boundary is also marked by an enrichment of polycyclic aromatic hydrocarbons, which, in the absence of charcoal peaks, we interpret as an indication of incomplete combustion of organic matter by ascending flood basalt lava. We conclude that the terrestrial vegetation shift is so severe and wide ranging that it is unlikely to have been triggered by greenhouse warming alone. Instead, we suggest that the release of pollutants such as sulphur dioxide and toxic compounds such as the polycyclic aromatic hydrocarbons may have contributed to the extinction.

Ocean acidification triggered by Siberian Trap volcanism has been implicated as a kill18 mechanism for the Permo-Triassic mass extinction, but evidence for an acidification event 19 remains inconclusive. To address this, we present a high resolution seawater pH record across 20 this interval, utilizing boron isotope data combined with a quantitative modeling approach. In the 21 latest Permian, the alkalinity of the ocean increased, priming the Earth system with a low level of 22 atmospheric CO 2 and a high ocean buffering capacity. The first phase of extinction was 23 2 coincident with a slow injection of isotopically light carbon into the atmosphere-ocean, but the 24 ocean was well-buffered such that ocean pH remained stable. During the second extinction pulse, 25 however, a rapid and large injection of carbon overwhelmed the buffering capacity of the ocean, 26causing an abrupt and short-lived acidification event that drove the preferential loss of heavily 27 calcified marine biota. kyrs (2) and can be resolved into two distinct marine extinction pulses, with the respective kill 37 mechanisms appearing to be ecologically selective (3). The first occurred in the latest Permian 38 (Extinction Pulse 1; EP1) and was followed by an interval of temporary recovery before the 39 second pulse (EP2) which occurred in the earliest Triassic. The direct cause of the mass 40 extinction is widely debated with a diverse range of overlapping mechanisms proposed, 41 including widespread water column anoxia (4), euxinia (5), global warming (6) and ocean 42 acidification (7). 43Models of PTB ocean acidification suggest that a massive, and rapid, release of CO 2 from 44 Siberian Trap volcanism, acidified the ocean (7). Indirect evidence for acidification comes from 45 the interpretation of faunal turnover records (3, 8), potential dissolution surfaces (9) and Ca 46 3 isotope data (7). A rapid input of carbon is also potentially recorded in the negative carbon 47 isotope excursion (CIE) that characterizes the PTB (10, 11) . The interpretation of these records 48 is, however, debated (12), and of great importance to understanding the current threat of 49 anthropogenically-driven ocean acidification (11). 50Here, we test the ocean acidification hypothesis by presenting a novel proxy record of 51 ocean pH across the PTB, using the boron isotope composition of marine carbonates ( 11 additional counterbalancing alkalinity flux. This is consistent with independent proxy data (6). 129The alkalinity source may have been further increased through soil loss (26) carbon to the atmosphere, yet remarkably, the acidification event occurs after the decline in  13 C, 139when  13 C has rebounded somewhat and is essentially stable (Fig. 2). 140Unlike the first carbon injection, the lack of change in  13 C at this time rules out very 141 13 C-depleted carbon sources, because no counterbalancing strongly 13 C-enriched source exists.

Psiloceras spelae tirolicum. The "Golden Spike" was fixed at Kuhjoch East. The section displays a high and continuous sedimentation rate with a constant facies trend across the boundary level. Other bio-events include the FO of the aragonitic foraminifer Praegubkinella turgescens, and of diverse ostracod species 1.0-3.40 cm below the FO of P. spelae and 3.2 m below P. spelae occurs the continental palynomorph Cerebropollenites thiergartii. Because of the lack of other terrestrial microfloral events this is yet the FO event closest to the FO of P. spelae and allows a correlation with nonmarine sediments. The δ 13 C org record shows a strong initial negative excursion at the boundary between the Kössen and Kendlbach formations, 5.8 m (Kuhjoch W) below the T-J boundary, a shift to more positive δ 13 C org in the Schattwald Beds and a gradual decline to more negative values at the transition of the Schattwald Beds to the proximate Tiefengraben Mb. The stratotype point lies within a zone of smaller negative and positive δ 13 C org peaks, which is superimposed on a longer lasting main negative shift. According to recent investigations, the radiometric age of the T-J boundary is about 201,3 Ma.

Figure 1. Paleogeographic reconstruction of Griesbachian indicating approximate positions of localities mentioned in text: 1-western United States; 2-northern Italy; 3-Wadi Wasit; 4-Salt Ranges of Pakistan; 5-southern Tibet. Paleogeography after Scotese (1994); land areas shaded, shallow-shelf seas indicated by dotted line.

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Multiple episodes of extensive oceanic anoxia delayed the marine ecosystem recovery from the latest Permian mass extinction.

The taxonomy, diversity, evolutionary lineages, and stratigraphical distributions of Middle and early Late Triassic conodonts are reviewed and re-evaluated. Twentyfive genera are recognized in the Middle and early Late Triassic, including a new genus cited in open nomenclature. Of these, 24 genera are assigned to two families and seven subfamilies. The family Gondolellidae consists of the subfamilies Cornudininae, Epigondolellinae, Neogondolellinae, Novispathodinae, Paragondolellinae and Pseudofurnishiinae. The family Gladigondolellidae is monotypic, consisting of the subfamily Gladigondolellinae. The genus Neostrachanognathus is not assigned to any family or subfamily as its origin is unclear. Conodont provincialism was low in the early Anisian, but from the late Anisian faunistic differences started to increase and became stronger during the early Ladinian, reaching a peak around the mid-Ladinian. Provincialism remained strong until the earliest Carnian and changed to an all-Triassic low in the early Tuvalian. The provincialism between North America and Tethys rebounded on the specific level during the late Tuvalian. Diversities on generic and specific levels have been established, and two major conodont diversity cycles are recognized: the first ranges from the Bithynian (early Anisian) to the Julian (late early Carnian), and the second is restricted to the Tuvalian (late Carnian).