We consider the design of an optimal superlattice thermoelectric generator via the energy bandpass filter approach. Various configurations of superlattice structures are explored to obtain a bandpass transmission spectrum that approaches the ideal "boxcar" form, which is now well known to manifest the largest efficiency at a given output power. Using the non-equilibrium Green's function formalism coupled self-consistently with the Poisson's equation, we identify such an ideal structure and also demonstrate that it is almost immune to the deleterious effect of self-consistent charging and device variability. Analyzing various superlattice designs, we conclude that superlattices with a Gaussian distribution of the barrier thickness offers the best thermoelectric efficiency at maximum power. It is observed that the best operating regime of this device design provides a maximum power in the range of 0.32-0.46 M W/m 2 at efficiencies between 54%-43% of Carnot efficiency. We also analyze our device designs with the conventional figure of merit approach to counter support the results so obtained. We note a high zT el = 6 value in the case of Gaussian distribution of the barrier thickness. With the existing advanced thin-film growth technology, the suggested superlattice structures can be achieved, and such optimized thermoelectric performances can be realized.
Microscopic features of carrier localization, minibands, and spectral currents of InAs/GaSb based type-II superlattice (T2SL) mid-infrared detector structures are studied and investigated in detail. In the presence of momentum and phase-relaxed elastic scattering processes, we show that a self-consistent non-equilibrium Green’s function method within the effective mass approximation can be an effective tool to fairly predict the miniband and spectral transport properties and their dependence on the design parameters such as layer thickness, superlattice periods, temperature, and built-in potential. To benchmark this model, we first evaluate the band properties of an infinite T2SL with periodic boundary conditions, employing the envelope function approximation with a finite-difference discretization within the perturbative eight-band framework. The strong dependence of the constituent material layer thicknesses on the band-edge positions and effective masses, offers a primary guideline to design performance-specific detectors for a wide range of operation. Moving forward, we demonstrate that using a finite T2SL structure in the Green’s function framework, one can estimate the bandgap, band-offsets, density of states and spatial overlap which comply well with the results and the experimental data. Finally, the superiority of this method is illustrated via a reasonable estimation of the band alignments in barrier-based multi-color non-periodic complex T2SL structures. This study, therefore, provides deep physical insights into the carrier confinements in broken-gap heterostructures and sets a perfect stage to perform transport calculations in a full-quantum picture.
In this work, we aim to design a heterostructure based nanoscale thermoelectric generator that can maximize the waste-heat conversion efficiency at a given output power. The primary objective to be achieved for this is to realize a boxcar-shaped (bandpass) electronic transmission function (R. S. Whitney, Phys. Rev. Lett. 112, 130601 (2014)). In order to achieve that, we propose the use of an electronic analog of optical Fabry-Pérot cavity over a central resonant tunneling structure. We further explore the optimum design possibilities by varying the geometry of the cavity wall to ensure a nearly perfect bandpass energy filtering of electrons. Based on our findings, we propose a general design guideline to realize such transmission and demonstrate that such devices can be excellent thermoelectric generators compared to the existing proposals in terms of boosting the output power without a cost in efficiency. It is theoretically demonstrated using the non-equilibrium Green's function technique coupled with self-consistent charging effects that an enhancement in the maximum output power up to 116% can be achieved through this scheme at a 10% higher efficiency as compared to resonant tunneling based devices. Furthermore, an elaborate comparative study of the linear response parameters is also presented and explained in terms of the physical transport properties. This study suggests an optimal device design strategy for an improved thermoelectric generator and sets the stage for a new class of thermoelectric generators facilitated via transmission lineshape engineering. arXiv:1902.07547v2 [cond-mat.mes-hall]
Development of chemical and biochemical sensors is the current need of the society. In this report, we present our investigation on the development of a label-free fibre-optic biosensor based on evanescent wave absorbance to detect the presence of analytes such as bacteria, virus and some clinically important proteins. A simple UV-LED (280 nm) and photodetector combination along with a fibre probe was used for developing cost-effective, user-friendly and field applicable device. To improve the sensitivity of the detection technique, the probe design was modified and the U-bent probe was fabricated by simple procedure. Further, to overcome the problems for using UV light source in the fibre, the localized surface plasmon resonance of noble metal nanoparticles at visible wavelength was exploited as a sensing medium for the biochemical reactions. Our systematic studies in this regard presented in this communication may bring the excitement for developing the waterborne pathogen detection device for house-hold as well as field applications.
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