Recent studies suggest that the cosmological constant affects the gravitational bending of photons although the orbital equation for light in Schwarzschild-de Sitter space time is free from cosmological constant. Here we argued that the very notion of cosmological constant independency of photon orbit in the Schwarzschild-de Sitter space time is not proper. Consequently the cosmological constant has some clear contribution to the deflection angle of light rays. We stressed the importance of the study of photon trajectories from the reference objects in bending calculation, particularly for asymptotically non-flat space-time. When such an aspect is taken in to consideration the contribution of cosmological constant to the effective bending is found to depend on the distances of the source and the reference objects.PACS numbers: 95.30.Sf, 98.80.Es

The curcumin is a well-known antioxidant that can scavenge free radicals efficiently. The methyl free radicals, generated by the metabolism of various genotoxic compounds such as hydrazines and peroxides, can methylate various sites in DNA. Herein, we have carried out density functional theory calculations to investigate the scavenging activity of curcumin toward the methyl and ethyl radicals through radical adduct formation (RAF), hydrogen atom transfer (HAT) and single electron transfer (SET) mechanisms. The SET mechanism is found to be highly endergonic and so not viable. Our calculations show that the curcumin can scavenge methyl radicals through both RAF and HAT mechanisms but RAF would be preferred over the HAT. Further, it is found that the curcumin can scavenge methyl radicals more efficiently as compared to ethyl radicals through RAF mechanism.

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