SAPO-34 nanocrystals with sizes of 50–150 nm were obtained via steam-assisted crystallization (SAC) for 5 h at 200 °C from two types of aluminum precursors—aluminum isopropoxide and boehmite. A reaction mixture composition with a small amount of organic template tetraehylammonium hydroxide (TEAOH) was used with the molar ratio TEAOH/Al2O3 = 1/1. The alumina precursor type and duration of the SAC (5 and 24 h) on the crystal size, texture, and acid properties were investigated. The SAPO-34 nanocrystals that we obtained possess a large micropore volume of 0.22–0.24 cm3/g and a specific surface area of 651–695 m2/g. When the crystallization was prolonged for up to 24 h, a SAPO-18 structure appeared, but the micropore and mesopore volumes changed insignificantly. Using boehmite as the aluminum precursor led to higher mesoporosity of the material but a little bit lower acidity when compared with the samples prepared from aluminum isopropoxide. In addition, the method proposed was used for preparing a SAPO-34-coated aluminum adsorber heat exchanger. Thus, the synthesis method proposed is affordable and effective to prepare SAPO-34 highly crystalline nanoparticles, with no need for post-synthetic procedures as the mother liquor separation from nanocrystals.
Adsorption energy storage is a promising resource-saving technology that allows the rational use of alternative heat sources. One of the most important parts of the adsorption heat accumulator is the adsorber heat exchanger. The parameters of heat transfer in this unit determine how fast heat from an alternative energy source, such as the Sun, will be stored. For the design of adsorption heat accumulators, plate fin heat exchangers are mainly used. In this paper, the procedure for the estimation of the global heat transfer coefficient for the adsorber heat exchanger depending on its geometry is considered. The heat transfer coefficient for a LiCl/SiO2 sorbent flat layer under conditions of heat storage stage was measured. Based on these data, the global heat transfer coefficients for a number of industrial heat exchangers were theoretically estimated and experimentally measured for the adsorption cycle of daily heat storage. It was shown that theoretically obtained values are in good agreement with the values of the global heat transfer coefficients measured experimentally. Thus, the considered technique makes it possible to determine the most promising geometry of the plate fin heat exchanger for a given adsorption heat storage cycle without complicated experiments.
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