Thermal decomposition of Cp2ZrMe(1-bromobenzocyclobutenyl) yields the η2-cyclobutadiene
complex Cp2Zr(η2-benzocyclobutadiene)(PMe3), which
cycloadds alkenes, nitriles, and t-BuNC, in the last case
giving a novel diamino−Dewar-naphthalene complex.
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