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▪ Abstract  The enigma of continental plateaus formed in the absence of continental collision is embodied by the Altiplano-Puna, which stretches for 1800 km along the Central Andes and attains a width of 350–400 km. The plateau correlates spatially and temporally with Andean arc magmatism, but it was uplifted primarily because of crustal thickening produced by horizontal shortening of a thermally softened lithosphere. Nonetheless, known shortening at the surface accounts for only 70–80% of the observed crustal thickening, suggesting that magmatic addition and other processes such as lithospheric thinning, upper mantle hydration, or tectonic underplating may contribute significantly to thickening. Uplift in the region of the Altiplano began around 25 Ma, coincident with increased convergence rate and inferred shallowing of subduction; uplift in the Puna commenced 5–10 million years later.

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The recognition of accreted terranes and their importance in orogenesis has spurred the search for allochthonous fragments along the western and southern margins of South America. Here we present stratigraphic and petrologic data from Chile and Argentina between 29° and 33°S latitude that demonstrate the “suspect” nature of several major terranes, which we infer to have been accreted during the Paleozoic. Three lower‐middle Paleozoic terranes are described (from east to west): (1) the Pampeanas terrane, a Cambrian‐Devonian magmatic and metamorphic province built on late Precambrian basement at the margin of South America, (2) the Precordillera terrane, a Cambrian‐Devonian shelf‐slope‐oceanic basin assemblage bounded by mélanges on both sides and bearing many stratigraphic similarities to the lower‐middle Paleozoic of the Northern Appalachians, and (3) the “Chilenia” terrane, which has largely been obliterated by late Paleozoic magmatism and metamorphism. The distribution of Carboniferous continental, deltaic, and marine strata demonstrates that these three terranes were sutured together and part of South America by the end of the Devonian. Subsequent Permo‐Carboniferous plate interactions more closely resembled the modern Andean margin, with eastward subduction, accretionary prism formation, and minor terrane emplacement exposed along the present coast of Chile and eastward migrating arc magmatism from the present coast of Chile to western Argentina.

The spatial distribution of some major and trace element and isotopic characteristics of backarc Plio‐Quaternary basaltic to high‐Mg andesitic (51% to 58% SiO2) lavas in the southern Puna (24°S to 27°S) of the Central Andean Volcanic Zone (CVZ) reflect varying continental lithospheric thickness and the thermal state of the underlying mantle wedge and subducting plate. These lavas erupted from small cones and fissures associated with faults related to a change in the regional stress system in the southern Puna at ≈ 2 to 3 Ma. Three geochemical groups are recognized: (1) a relatively high volume intraplate group (high K; La/Ta ratio <25) that occurs over a thin continental lithosphere above a gap in the modern seismic zone and represents the highest percentage of mantle partial melt, (2) an intermediate volume, high‐K calc‐alkaline group ( La/Ta ratio >25) that occurs over intermediate thickness lithosphere on the margins of the seismic gap and behind the main CVZ and represents an intermediate percentage of mantle partial melt, and (3) a small‐volume shoshonitic group (very high K) that occurs over relatively thick continental lithosphere in the northeast Puna and Altiplano and represents a very small percentage of mantle partial melt. Mantle‐generated characteristics of these lavas are partially overprinted by mixing with melts of the overlying thickened crust as shown by the presence of quartz and feldspar xenocrysts, negative Eu anomalies (Eu/Eu < 0.90; most < 0.80), and radiogenic Sr (> 0.7055) and Pb and nonradiogenic Nd ( εNd < −0.4) isotopic ratios. Mixing calculations show that the lavas generally contain more than 20% to 25% crustal melt. The eruption of the intraplate group mafic lavas, the change in regional stress orientation, and the high elevation of the southern Puna are suggested to be the result of the late Pliocene mechanical delamination of a block (or blocks) of continental lithosphere (mantle and possibly lowermost crust). The loss of this lithosphere resulted in an influx of asthenosphere that caused heating of the subducting slab and yielded intraplate basic magmas that produced extensive melting at the base of the thickened crust. Heating of the subducting slab led to formation of the seismic gap and trenchward depletion of the slab component. Backarc calc‐alkaline group lavas erupted on the margins of this delaminated block, whereas shoshonitic group lavas erupted over a zone of relatively thick nondelaminated lithosphere to the north.