Ac ombination of soft lithographic printing and soft templating has been used to fabricate high-resolution interdigitatedm icro-supercapacitors (MSC). Surfactant-assisted self-assembly produces high surface area orderedm esoporous carbons(490 m 2 g À1). For the first time, such precursors have been printed by nano-imprint lithography as microdevices with al ine width of only 250 nm and as pacing of only 1 mm. The devices are crack-free with low specific resistance(1.2 10 À5 Wm) and show good device capacitance up to 0.21 Fcm À3 .
Two new carboxylate silver(I) complexes, namely [Ag2(C4H6O4N)]NO3·H2O or [Ag2(HIDA)]NO3·H2O with IDA = iminodiacetate (1) and Ag6(C6H6O6N)2 or Ag6(NTA)2 with NTA = nitrilotriacetate (2) are synthesized and characterized by X‐ray powder diffraction, thermal analysis and infrared spectroscopy. Rietveld refinement reveals [Ag2(HIDA)]NO3·H2O to form a 2D coordination polymer while Ag6(NTA)2 forms a 3D network, both featuring short Ag(d10)–Ag(d10) contacts. The resulting complexes are suitable precursors for the printing of silver structures at low temperature, in particular for micro and submicrometer patterns obtained via nanoimprint lithography. The patterns reveal low specific resistivity (ρ ≈ 10–7 Ω m) and good transmittance (> 50 %) in the visible range enabling applications in optoelectronic devices.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.