The methanation of carbon dioxide (CO2) via the Sabatier reaction is an exothermic process that needs the continuous removal of the heat produced for avoiding the sintering of the catalyst. A novel milli-channel reactor with internal diameter of each channel in the millimeter size has been designed, manufactured and tested for the Sabatier reaction. Thanks to its configuration, this reactor could control effectively the heat generated by the reaction, attaining an intensification of the process. A CFD model was used to study the reaction phenomena occurring inside the reactor and the corresponding heat transfers. The kinetic parameters of the reaction have been obtained, and employing different process condition (different temperatures, pressures and gas flow rates) the results obtained have been studied. At the evaluated parameters, the CFD model fits the experimental results in the developed reactor.
This work considers virtualization of the wireless medium as a mean to share common network physical infrastructure by different Virtual Operators (VO) based on a Time Division Multiple Access (TDMA) virtualization technique. We have developed a Wireless Medium Virtualization Framework (WMVF) to analyze the performance of a variable number of VOs (with one or more types of traffic) accessing to the same wireless medium through the same wireless node in a coordinated way. Extensive simulations have been carried out to assess the impact of wireless medium virtualization based on relevant parameters such as the type of traffic, the number of VOs and the specific wireless technology. Delay, jitter and the utilization of the network are the metrics used in this paper to show the potential and limitations of wireless virtualization as a way to increase network usage. This work has been carried out partially inside the European Project 4WARD (FP7 Project reference: 216041)
A novel multichannel minireactor with channel internal diameter in the range of millimeters has been conceptually designed and constructed. Its configuration confers to the new concept reactor some features and advantages compared to conventional fixed-bed reactors g.e. better mass-transfer, avoid hot-spots formation, increased performance (10-20%). Consequently, this new reactor concept is ideal to be applied to exothermic reactions such as the Sabatier reaction that demands continuous removal of the heat produced to avoid hot-spot formation and the sintering of the catalyst. Thanks to its configuration, this reactor could control effectively the heat generated by the reaction and several tests were carried out to validate the reactor features. The results obtained demonstrate that the catalysts activity in the reaction is improved with the application of the novel reactor respect the conventional fixed-and fluidized-bed ones and neither catalyst sintering, nor pressure drop was appreciated during the catalytic tests. At the best reaction conditions, Tecnalia's multichannel minireactor can handle 820 Nm 3 /h of CO 2 per square meter of channel section showing the enormous potential of the new reactor concept.
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