The search for impact‐tolerant, light‐weight flexible materials has challenged materials scientists and engineers for decades. In this quest, many researchers have focused on studying natural armor as a guide to propose bioinspired materials with enhanced properties. The energy dissipation and flexibility mechanisms activated at different hierarchical structural levels of natural systems are used here as a guide to improve the energy and flexibility of synthetic materials. In particular, fish scales and osteoderms are selected as proper biological models to develop a novel family of cost‐effective bioinspired protecto‐flexible (Pf) materials. Furthermore, a bullet‐proof protecto‐flexible prototype is manufactured and tested. The ballistic tests suggest that under real stringent conditions, the system is capable of absorbing high levels of energy while remaining flexible enough to allow movement to the user. Remarkably, the material system developed allows its implementation into realistic high volumes of production with low added costs. Consequently, the proposed strategy for developing bioinspired Pf materials will enable the development of the next generation of high‐performance impact‐resistant materials.

The quest for new light-weight materials with superior mechanical properties is a goal of materials scientists and engineers worldwide. A promising route in this pursuit is drawing inspiration from nature to design and develop materials with enhanced properties. By emulating the graded mineral content and hierarchical structure of fish scales of the Arapaima gigas from the nano to macro scales, we were able to develop bioinspired laminated composites with improved impact resistance. Activated by the addition of nano-particles of Al 2 O 3 and nano-layers of TiN to a thermoplastic fiber substrate, new energy dissipation mechanisms operating at the nanoscale enhanced the energy absorption and stiffness of the bioinspired material. Remarkably, the newly developed materials are easily transferred to the industry with minimum associated manufacturing costs.