Real-time live cell imaging and quantification of biothiols dynamics are important for understanding the pathophysiological process. However, it is still challenging in the design and synthesis of rational probes that...
A series of imine-based macrocycles and cages has been synthesized using the gem-dimethyl effect as a platform. Following this strategy, imine-based macrocyclization could be performed even at higher concentration.
Metal-Organic Frameworks(MOFs) synthesized from ligands more than ten co-ordinating sites may offer material applications due to their structural architecture. Herein, a synthesis of metal-organic framework is reported from a ligand featuring 12-aryl carboxylic acid groups appended on a hexaphenylbenzene and s-block element potassium. The synthesized MOF was characterized by thermogravimetric analysis, infrared spectroscopy and X-diffraction studies. The X-ray crystal structure of MOF was shown to have a significant number of trapped and coordinated water molecules in its three-dimensional framework.
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