The X-ray satellite spectra arising due to 2p 3/2 -1 3x -1 -3x -1 3d -1 (x ≡ s, p, d) transition array, in elements with Z = 40 to 48, have been calculated, using available Hartree-Fock-Slater (HFS) data on 1s -1 -2p -1 3x -and 2p 3/2 -1 -3x -1 ,3x -1 Auger transition energies. The relative intensities of all the possible transitions have been estimated by considering cross -sections for the Auger transitions simultaneous to a hole creation and then distributing statistically the total cross sections for initial two hole states 2p 3/2 -1 -3x -1 amongst various allowed transitions from these initial states to 3x -1 3d -1 final states by Coster-Kronig (CK) and shake off processes. In both these processes initial single hole creation is the prime phenomenon. Each transition has been assumed to give rise to a Gaussian line and the overall spectrum has been computed as the sum of these Gaussian curves. The calculated spectra have been compared with the measured satellite energies in Lα 1 spectra. Their intense peaks have been identified as the observed satellite lines. The peaks in the theoretical satellite spectra were identified as the experimentally reported satellites α 3 , α 4 and α 5 , which lie on the highenergy side of the Lα 1 dipole line.
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