This study was focused on a facile synthesis and comprehensive characterization of carboxymethyl cellulose (CMC)‐based hydrogel and their potential absorption. CMC reacted with AlIII as an ionic crosslinker to produce physical hydrogels with better gel strength but gave a low water absorption (WAC). To elucidate this question, we fabricated both the CMC hydrogel and its nanocomposite hydrogel incorporating nano‐size calcium carbonate (NCC) particles using a two‐step process. The AlIII‐ crosslinked CMC hydrogel was subsequently filled with NCC particles to give CMC/NCC nanocomposite hydrogels. The CMC/NCC1 hydrogel with NCC 1 %wv−1 gave a three‐fold higher equilibrium WAC. To achieve an insight structure‐property‐function relation, CMC hydrogels were characterized for physically crosslinking interaction. FT‐IR confirmed that AlIII ion reacts with the negative charges of carboxylate groups on the CMC chains to form the network structure via bidentate coordination. XPS data of the CMC hydrogels agreed well with the spectroscopic data. The resonance peaks of the C−O of substituent groups−CH2COO− were shifted upward to 177.9 ppm due to the incorporation of NCC. The higher chain flexibility (low tanδ) in CMC/NCC hydrogel with NCC 1 %wv−1 produced the higher WAC than did the composite hydrogel with NCC 5 %wv−1 adding. The CMC hydrogels were explored whether they are promisingly sustainable adsorbent for dye adsorption from Sappan wood extract while its CMC/NCC hydrogel rendered for better water absorption. Morphological studies revealed that NCC particles distributed mostly on the CMC surfaces to produce nanostructured composites with some particles penetrating through hydrogel pores. The specific surface areas of the CMC hydrogel increased with NCC amounts with lower WACs due to gel stiffness. The CMC hydrogels were confirmed as a promisingly sustainable adsorbent for dye adsorption from Sappan wood extract while its CMC/NCC hydrogel rendered for better water absorption which should be applicable for the dye concentration before CMC hydrogel dye adsorption.
Water unavailability and shortage are severe problems in agriculture, particularly in loamy sandy to sandy soil, since they inhibit plant growth, resulting in a low crop yield. Using biocompatible hydrogels with good water absorption and retention properties is essential to improve plant growth under unfavorable situations. This work aimed to investigate the influence of the carboxymethyl cellulose/nano-calcium carbonate (CMC/NCC) composite amended in the loamy sand soil on maize growth in a pot experiment. Two types of CMC hydrogels with 1 or 5% wv–1 of NCC, designated as CMC/NCC1 and CMC/NCC5 composite hydrogels, respectively, were selected in this study. Incorporating NCC nanoparticles into the physically crosslinked CMC hydrogel networks exhibited the ability to increase water absorption of the pristine and nanocomposite CMC hydrogels. We investigated the properties of hydrogels of different compositions and dosages added to cause increased water absorption capacity (WAC), water holding capacity (WHC), and carbon dioxide (CO2) evolution. The CMC/NCC hydrogels had better swelling capacity than those of the pristine CMC hydrogels at all pHs. The amendment of hydrogels in loamy sand soil enhanced the soil WHC. The CO2 evolution gradually increased with incubation time in the order of CMC > CMC/NCC1 > CMC/NCC5 > the control soil. The chlorophyll contents, the biomasses of the above- and below-ground parts, and root length were observed as the determining parameters of maize growth. Although the total chlorophyll contents of maize leaves did not significantly change with hydrogel supplementations, the root biomass and cumulative root length of the maize grown in the soil amended with hydrogels were significantly lower than that of untreated soil without changing the above-ground biomass. This suggests that the maize plant growing in the loamy sand soil amended with CMC/NCC hydrogels could affect the allocation of carbon without changing the overall crop yield. Thus, the CMC/NCC hydrogels can be used as an alternative soil amendment for agricultural applications in the loamy sand soil to maintain plant growth.
Summary: This research is to study the potential of using polystyrene nanoparticles and chitosan solution to increase the anti-bacterial activity on cotton fabrics prepared by a conventional pad-dry-cure method. Firstly, cotton fabrics were coated with chitosan solutions at the concentrations of 0.1, 0.5, and 1.0 (%w/v) and tested for the antibacterial property which was determined by clear zone measurement and viable count assay using Escherichia coli (ATCC 25922) as a tested microorganism. The results showed that, the percentage bacterial reductions were 87.2, 86.3, and 48.5%, respectively, when the cotton fabrics was coated only with chitosan solution. When polystyrene nanoparticle solution was coated onto cotton fabrics prior to coating with chitosan solutions at the concentrations of 0.1, 0.5, and 1.0 (%w/v), the percentage bacterial reductions were 90.3, 90.8, and 65.5%, respectively. This indicated that coating the cotton fabrics with polystyrene nanoparticles prior to chitosan coating would remarkably increase the antibacterial activity. The scanning electron micrographs showed that polystyrene nanoparticles were aggregated and inserted in between the interfiber spacings. The thin film of chitosan was also observed on the surface of cotton fabrics and hydrophobic property of the fabrics was tested via contact angle measurement.
Degenerate primer sets were designed to reveal biodiversity of genes using dynamic pattern matching. Bacterial nucleotide sequences were randomly selected from ten different genus and used to find universal primers for bacterial gene selection. Aligned sequences from different bacterial nucleotides were entered into the system consisted of three steps: data reformation, primer design, and property filtering. First, degenerate and consensus sequences were calculated using statistical models. The results were combined with Gibbs Free Energy to design and select the most appropriate sequences as a series of primer sets. Moreover, users can also adjust their own criteria for each primer set. The results indicate that the degenerate primers designed by our proposed system were proved to be positive.
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