Developing cost-effective and efficient oxygen evolution reaction (OER) catalysts is very important for electrochemical water splitting devices. Herein, hollow Co-based layered double hydroxide (LDH) decorated with Ag nanoparticles (Ag@HÀ Co-À LDH) was constructed using ion etching of zeolitic imidazolate frameworks-67 (ZIF-67), followed by simple stirring with Ag salts. Hollow double layered structure could expose rich active centers and improve electron transfer and mass transport. Meanwhile, the introduction of Ag species greatly increases the electrical conductivity and enhances cobalt species to form highly catalytically active Co 4 + . Therefore, the as-obtained Ag@HÀ CoÀ LDH exhibits a distinguished OER activity with a low overpotential of 298 mV to provide an oxygen evolution current density of 10 mA cm À 2 , which is superior to that of CoÀ LDH and even commercial RuO 2 .