Enhanced performance of an inverted‐type polymer solar cell is reported by controlling the surface energy of a zinc oxide (ZnO) buffer layer, on which a photoactive layer composed of a polymer:fullerene‐derivative bulk heterojunction is formed. With the approach based on a mixed self‐assembled monolayer, the surface energy of the ZnO buffer layer can be controlled between 40 mN m−1 and 70 mN m−1 with negligible changes in its work function. For the given range of surface energy the power conversion efficiency increases from 3.27% to 3.70% through enhanced photocurrents. The optimized morphology obtained by surface energy control results in the enhanced photocurrent and transmission electron microscopy analysis verifies the correlation between the surface energy and the phase morphology of the bulk heterojunction. These results demonstrate that surface energy control is an effective method for further improving the performance of polymer solar cells, with potentially important implications for other organic devices containing an interface between a blended organic active layer and a buffer or an electrode layer.
There are growing opportunities and demands for image sensors that produce higher-resolution images, even in low-light conditions. Increasing the light input areas through 3D architecture within the same pixel size can be an effective solution to address this issue. Organic photodiodes (OPDs) that possess wavelength selectivity can allow for advancements in this regard. Here, we report on novel push-pull D-π-A dyes specially designed for Gaussian-shaped, narrow-band absorption and the high photoelectric conversion. These p-type organic dyes work both as a color filter and as a source of photocurrents with linear and fast light responses, high sensitivity, and excellent stability, when combined with C60 to form bulk heterojunctions (BHJs). The effectiveness of the OPD composed of the active color filter was demonstrated by obtaining a full-color image using a camera that contained an organic/Si hybrid complementary metal-oxide-semiconductor (CMOS) color image sensor.
A bulk-heterojunction
(BHJ) structure of organic semiconductor
blend is widely used in photon-to-electron converting devices such
as organic photodetectors (OPD) and photovoltaics (OPV). However,
the impact of the molecular structure on the interfacial electronic
states and optoelectronic properties of the constituent organic semiconductors
is still unclear, limiting further development of these devices for
commercialization. Herein, the critical role of donor molecular structure
on OPD performance is identified in highly intermixed BHJ blends containing
a small-molecule donor and C60 acceptor. Blending introduces
a twisted structure in the donor molecule and a strong coupling between
donor and acceptor molecules. This results in ultrafast exciton separation
(<1 ps), producing bound (binding energy ∼135 meV), localized
(∼0.9 nm), and highly emissive interfacial charge transfer
(CT) states. These interfacial CT states undergo efficient dissociation
under an applied electric field, leading to highly efficient OPDs
in reverse bias but poor OPVs. Further structural twisting and molecular-scale
aggregation of the donor molecules occur in blends upon thermal annealing
just above the transition temperature of 150 °C at which donor
molecules start to reorganize themselves without any apparent macroscopic
phase-segregation. These subtle structural changes lead to significant
improvements in charge transport and OPD performance, yielding ultralow
dark currents (∼10–10 A cm–2), 2-fold faster charge extraction (in μs), and nearly an order
of magnitude increase in effective carrier mobility. Our results provide
molecular insights into high-performance OPDs by identifying the role
of subtle molecular structural changes on device performance and highlight
key differences in the design of BHJ blends for OPD and OPV devices.
Organic photodetectors (OPDs) exhibit superior spectral responses but slower photoresponse times compared to inorganic counterparts. Herein, we study the light-intensity-dependent OPD photoresponse time with two small-molecule donors (planar MPTA or twisted NP-SA) co-evaporated with C60 acceptors. MPTA:C60 exhibits the fastest response time at high-light intensities (>0.5 mW/cm2), attributed to its planar structure favoring strong intermolecular interactions. However, this blend exhibits the slowest response at low-light intensities, which is correlated with biphasic photocurrent transients indicative of the presence of a low density of deep trap states. Optical, structural, and energetical analyses indicate that MPTA molecular packing is strongly disrupted by C60, resulting in a larger (370 meV) HOMO level shift. This results in greater energetic inhomogeneity including possible MPTA-C60 adduct formation, leading to deep trap states which limit the low-light photoresponse time. This work provides important insights into the small molecule design rules critical for low charge-trapping and high-speed OPD applications.
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