Nitrate (NO3-) is one of the most harmful contaminants in the groundwater, and it causes various health problems. Bimetallic catalysts, usually palladium (Pd) coupled with secondary metallic catalyst, are found to properly treat nitrate-containing wastewaters; however, the selectivity toward N2 production over ammonia (NH3) production still requires further improvement. Because the N2 selectivity is determined at the nitrite (NO2-) reduction step on the Pd surface, which occurs after NO3- is decomposed into NO2- on the secondary metallic catalyst, we here performed density functional theory (DFT) calculations and experiments to investigate the NO2- reduction pathway on the Pd surface activated by hydrogen. Based on extensive DFT calculations on the relative energetics among ∼100 possible intermediates, we found that NO2- is easily reduced to NO* on the Pd surface, followed by either sequential hydrogenation steps to yield NH3 or a decomposition step to N* and O* (an adsorbate on Pd is denoted using an asterisk). Based on the calculated high migration barrier of N*, we further discussed that the direct combination of two N* to yield N2 is kinetically less favorable than the combination of a highly mobile H* with N* to yield NH3. Instead, the reduction of NO2- in the vicinity of the N* can yield N2O* that can be preferentially transformed into N2 via diverse reaction pathways. Our DFT results suggest that enhancing the likelihood of N* encountering NO2- in the solution phase before combination with surface H* is important for maximizing the N2 selectivity. This is further supported by our experiments on NO2- reduction by Pd/TiO2, showing that both a decreased H2 flow rate and an increased NO2- concentration increased the N2 selectivity (78.6-93.6% and 57.8-90.9%, respectively).

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Nanoscale zerovalent iron (NZVI) is one of the most extensively studied nanomaterials in the fields of wastewater treatment and remediation of soil and groundwater. However, rapid oxidative transformations of NZVI can result in reduced NZVI reactivity. Indeed, the surface passivation of NZVI is considered one of the most challenging aspects in successfully applying NZVI to contaminant degradation. The oxidation of NZVI can lead to the formation of Fe II-bearing phases (e.g., Fe II O, Fe II (OH) 2 , Fe II Fe III 2 O 4) on the NZVI surface or complete oxidation to ferric (oxyhydr)oxides (e.g., Fe III OOH). This corrosion phenomenon is dependent upon various factors including the composition of NZVI itself, the type and concentration of aqueous species, reaction time and oxic/anoxic environments. As such, the coexistence of different Fe oxidation states on NZVI surfaces may also, in some instances, provide a unique reactive microenvironment to promote the adsorption of contaminants and their subsequent transformation via redox reactions. Thus, an understanding of passivation chemistry, and its related mechanisms, is essential not only for effective NZVI application but also for accurately assessing the positive and negative effects of NZVI surface passivation. The aim of this review is to discuss the nature of the passivation processes that occur and the passivation byproducts that form in various environments. In particular, the review presents: i) the strengths and limitations of state-of-the-art techniques (e.g., electron microscopies and X-ray based spectroscopies) to identify passivation byproducts; ii) the passivation mechanisms proposed to occur in anoxic and oxic environments; and iii) the effects arising from synthesis procedures and the presence of inorganics/organics on the nature of the passivation byproducts that form. In addition, several depassivation strategies that may assist in increasing and/or maintaining the reactivity of NZVI are considered, thereby enhancing the effectiveness of NZVI in contaminant degradation.

A new hematite-supported Pd-Cu bimetallic catalyst (Pd-Cu/hematite) was developed in order to actively and selectively reduce nitrate (NO3(-)) to nitrogen gas (N2). Four different iron-bearing soil minerals (hematite (H), goethite (G), maghemite (M), and lepidocrocite (L)) were transformed to hematite by calcination and used for synthesis of different Pd-Cu/hematite-H, G, M, and L catalysts. Their characteristics were identified using X-ray diffraction (XRD), specific surface area (BET), temperature programed reduction (TPR), transmission electron microscopy with energy dispersive X-ray (TEM-EDX), H2 pulse chemisorption, zeta-potential, and X-ray photoelectron spectroscopy (XPS). Pd-Cu/hematite-H exhibited the highest NO3(-) removal (96.4%) after 90 min, while a lower removal (90.9, 51.1, and 30.5%) was observed in Pd-Cu/hematite-G, M, and L, respectively. The results of TEM-EDX, and TPR analysis revealed that Pd-Cu/hematite-H possessed the closest contact distance between the Cu and Pd sites on the hematite surface among the different Pd-Cu/hematite catalysts. The high removal can be also attributed to the highly active metallic sites on its positively charged surface. The XPS analysis demonstrated that the amount of hydrogen molecules can have a pivotal function on NO3(-) removal and a ratio of nitrogen to hydrogen molecule (N:H) on the Pd sites can critically determine N2 selectivity.