For flexible displays, recovery and relaxation of acrylic pressure-sensitive adhesives (PSA) must be enhanced; however, only a few studies have focused on their optimization. High cross-linking density of the PSA leads to improved recovery but deteriorates the stress relaxation; thus, it is difficult to perform optimization by simply controlling the cross-linking density. Herein, it was determined that a UV-patterned PSA with both high and low cross-linking densities in a single layer enables the optimization of both recovery and relaxation. By introducing the UV-patterned PSA, the elasticity and recovery largely deteriorated but the stress relaxation was significantly improved, compared to that of the nonpatterned PSA, and this effect was enhanced with increases in the applied strain. Thereby, the recovery and relaxation were well-optimized with both values above 71% only at 300% strain. The recovery and relaxation of PSA had, respectively, a positive and negative correlation with the storage modulus.
The significance of concrete durability increases since RC (Reinforced Concrete) structures undergo degradation due to aggressive environmental conditions, which affects structural safety and serviceability. Steel corrosion is the major cause for the unexpected failure of RC structures. The main cause for the corrosion initiation is the ingress of chloride ions prevailing in the environment. Hence quantitative evaluation of chloride diffusion becomes very important to obtain a chloride diffusion coefficient and resistance to chloride ion intrusion. In the present investigation, 15 mix proportions with 3 water-to-binder ratios (0.37, 0.42, and 0.47) and 3 replacement ratios (0, 30, and 50%) were prepared for HPC (high-performance concrete) with fly-ash and ground granulated blast furnace slag. Chloride diffusion coefficient was measured under nonstationary condition. In order to evaluate the microstructure characteristics, porosity through MIP was also measured. The results of compressive strength, chloride diffusion, and porosity are compared with electrical charges. This paper deals with the results of the concrete samples exposed for only 2 months, but it is a part of the total test plan for 100 years. From the work, time-dependent diffusion coefficients in HPC and the key parameters for durability design are proposed.
Epoxy foam adhesives are widely used for weight reduction, watertight property, and mechanical reinforcement effects. However, epoxy foam adhesives have poor impact resistance at higher expansion ratios. Hence, we prepared an epoxy composite foam adhesive with core–shell rubber (CSR) particles to improve the impact resistance and applied it to automotive structural adhesives. The curing behavior and pore structure were characterized by differential scanning calorimetry (DSC) and X-ray computed tomography (CT), respectively, and impact wedge–peel tests were conducted to quantitatively evaluate the resistance to cleavage of the CSR/epoxy composite foam adhesives under impact. At 5 and 10 phr CSR contents, the pore size and expansion ratio increased sufficiently due to the decrease in curing rate. However, at 20 phr CSR content, the pore size decreased, which might be due to the steric hindrance effect of the CSR particles. Notably, at 0 and 0.1 phr foaming agent contents, the resistance to cleavage of the adhesives under the impact wedge–peel condition significantly improved with increasing CSR content. Thus, the CSR/epoxy composite foam adhesive containing 0.1 phr foaming agent and 20 phr CSR particles showed high impact resistance (EC = 34,000 mJ/cm2) and sufficient expansion ratio (~148%).
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