Maximum atom efficiency as well as distinct chemoselectivity is expected for electrocatalysis on atomically dispersed (or single site) metal centres, but its realization remains challenging so far, because carbon, as the most widely used electrocatalyst support, cannot effectively stabilize them. Here we report that a sulfur-doped zeolite-templated carbon, simultaneously exhibiting large sulfur content (17 wt% S), as well as a unique carbon structure (that is, highly curved three-dimensional networks of graphene nanoribbons), can stabilize a relatively high loading of platinum (5 wt%) in the form of highly dispersed species including site isolated atoms. In the oxygen reduction reaction, this catalyst does not follow a conventional four-electron pathway producing H2O, but selectively produces H2O2 even over extended times without significant degradation of the activity. Thus, this approach constitutes a potentially promising route for producing important fine chemical H2O2, and also offers opportunities for tuning the selectivity of other electrochemical reactions on various metal catalysts.

The surface chemistry of supported chromium catalysts (Cr/SiO, -AI , O, ) has been systematically investigated as a function of the support composition (Si : Al ratio) and the Cr oxide loading by a combination of diffuse reflectance spectroscopy (DRS), Raman spectroscopy (RS), X-ray Absorption spectroscopy (EXAFS-XANES) and temperature-programmed reduction (TPR). Combination of all the obtained results by these characterization techniques leads to a uniform interpretation and general picture of surface Cr. On hydrated surfaces, the molecular structure of the Cr oxide species depends on the isoelectric point of the oxide support and the Cr loading : more polymerized Cr oxide species correspond to higher Cr loading and silica content of the support. After calcination, the Cr oxide species are anchored onto the surface by reaction with surface hydroxy groups of the supports. On alumina the reaction starts with the most basic OH groups on alumina. This suggests that the anchoring process is an acid-base reaction. On calcined surfaces, the polymerization of the anchored Cr oxide species and the amount of Cr, O, clusters increases with silica content and Cr loading. Reduced Cr samples possess both Cr2+ and Cr3+, the relative concentrations of which are support and loading dependent: lower Cr2+ : Cr3+ ratios correspond to higher Cr loading and alumina content of the support.

Three-dimensional graphene architectures with periodic nanopores—reminiscent of zeolite frameworks—are of topical interest because of the possibility of combining the characteristics of graphene with a three-dimensional porous structure. Lately, the synthesis of such carbons has been approached by using zeolites as templates and small hydrocarbon molecules that can enter the narrow pore apertures. However, pyrolytic carbonization of the hydrocarbons (a necessary step in generating pure carbon) requires high temperatures and results in non-selective carbon deposition outside the pores. Here, we demonstrate that lanthanum ions embedded in zeolite pores can lower the temperature required for the carbonization of ethylene or acetylene. In this way, a graphene-like carbon structure can be selectively formed inside the zeolite template, without carbon being deposited at the external surfaces. X-ray diffraction data from zeolite single crystals after carbonization indicate that electron densities corresponding to carbon atoms are generated along the walls of the zeolite pores. After the zeolite template is removed, the carbon framework exhibits an electrical conductivity that is two orders of magnitude higher than that of amorphous mesoporous carbon. Lanthanum catalysis allows a carbon framework to form in zeolite pores with diameters of less than 1 nanometre; as such, microporous carbon nanostructures can be reproduced with various topologies corresponding to different zeolite pore sizes and shapes. We demonstrate carbon synthesis for large-pore zeolites (FAU, EMT and beta), a one-dimensional medium-pore zeolite (LTL), and even small-pore zeolites (MFI and LTA). The catalytic effect is a common feature of lanthanum, yttrium and calcium, which are all carbide-forming metal elements. We also show that the synthesis can be readily scaled up, which will be important for practical applications such as the production of lithium-ion batteries and zeolite-like catalyst supports.

Holely organic solid: Effective packing of the rigid macrocycle cucurbituril through CH⋅⋅⋅O hydrogen‐bonding and van der Waals interactions leads to a honeycomb‐like structure with unprecedented stability and porosity. It shows extraordinary sorption properties toward gases, particularly acetylene, which are comparable or superior to those of metal–organic frameworks in terms of storage capacity.

The novel fused Zn(II)porphyrin arrays (Tn, porphyrin tapes) in which the porphyrin macrocycles are triply linked at meso-meso, beta-beta, beta-beta positions have been investigated by steady-state and time-resolved spectroscopic measurements along with theoretical MO calculations. The absorption spectra of the porphyrin tapes show a systematic downshift to the IR region as the number of porphyrin pigments increases in the arrays. The fused porphyrin arrays exhibit a rapid formation of the lowest excited states (for T2, approximately 500 fs) via fast internal conversion processes upon photoexcitation at 400 nm (Soret bands), which is much faster than the internal conversion process of approximately 1.2 ps observed for a monomeric Zn(II)porphyrin. The relaxation dynamics of the lowest excited states of the porphyrin tapes were accelerated from approximately 4.5 ps for the T2 dimer to approximately 0.3 ps for the T6 hexamer as the number of porphyrin units increases, being explained well by the energy gap law. The overall photophysical properties of the porphyrin tapes were observed to be in a sharp contrast to those of the orthogonal porphyrin arrays. The PPP-SCI calculated charge-transfer probability indicates that the lowest excited state of the porphyrin tapes (Tn) resembles a Wannier-type exciton closely, whereas the lowest excited state of the directly linked porphyrin arrays can be considered as a Frenkel-type exciton. Conclusively, these unique photophysical properties of the porphyrin tapes have aroused much interest in the fundamental photophysics of large flat organic molecules as well as in the possible applications as electric wires, IR sensors, and nonlinear optical materials.

A new set of spectroscopic tools is proposed that may be used to distinguish antiaromatic compounds from their corresponding aromatic congeners. This prediction is based on a detailed analysis of the optical and photophysical properties of a matched set of expanded porphyrins. In particular, the antiaromatic porphyrinoids having [4n] π-electrons within their conjugation pathway exhibit distinct photophysical features that differ dramatically from what is observed for the corresponding aromatic congeners. The clear diagnostic differences seen between the antiaromatic and aromatic compounds leads us to propose that the spectroscopic methods detailed in this Perspective could emerge as general tools that may be used to characterize the electronic characteristics of complex systems for which a number of potential electronic states can be envisioned on the basis of simple line formulas or analyses of π-electron populations. W ith a storied history dating back to the days of early interest in benzene, the concept of aromaticity continues to excite the imagination of chemists, even as its importance has become increasingly apparent in fields as diverse of biomedicine and materials science. Not surprisingly, therefore, considerable effort has been devoted to exploring and understanding aromaticity. As a consequence, aromaticity has come to be defined in terms of five key experimental parameters, namely, energetics, structure, reactivity, magnetism, and spectroscopic features. 1 While the chemical and physical properties of many canonical aromatic systems have been investigated in detail, a complete understanding of the underlying structure-property relationships, including H€ uckel's [4n þ 2] rule and other types of quantitative indices of aromaticity, 2-7 still remains elusive. 8,9 This is even more true in the case of antiaromaticity.

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Femtosecond fluorescence anisotropy measurements for a variety of cyclic porphyrin arrays such as Zn(II)porphyrin m-trimer and hexamer are reported along with o-dimer and monomer as reference molecules. In the porphyrin arrays, a pair of porphyrin moieties are joined together via triphenyl linkage to ensure cyclic and rigid structures. Anisotropy decay times of the porphyrin arrays can be well described by the Förster incoherent excitation hopping process between the porphyrin units. Exciton coupling strengths of 74 and 264 cm(-1) for the m-trimer and hexamer estimated from the observed excitation energy hopping rates are close to those of B800 and B850, respectively, in the LH2 bacterial light-harvesting antenna. Thus, these cyclic porphyrin array systems have proven to be useful in understanding energy migration processes in a relatively weak interaction regime in light of the similarity in overall structures and constituent chromophores to natural light-harvesting arrays.