Four new hydrothermal vent fields were discovered on the slow spreading Central Indian Ridge (8–12°S; Segments 1–3), all located off‐axis on abyssal hill structures or Ocean Core Complexes (OCCs). Each site was characterized using seafloor observation (towed camera system), plume chemistry (Fe, Mn, and CH4; Conductivity, Temperature, and Depth sensor [CTD]/Miniature Autonomous Plume Recorder [MAPR]), and rock sampling (TVgrab/dredges). Different styles of venting on each segment reflect different geological settings, rock types, likely heat sources, and fluid pathways. The segment 1 field was located on the western flank of the axial valley at the base of OCC‐1‐1. High‐temperature venting was inferred from plume characteristics and extensive seafloor sulfide mineralization, but only diffuse venting was observed. This site appears to be a magmatic‐influenced basaltic‐hosted system despite its off‐axis location. Two low‐temperature diffusely venting sites were located on abyssal hills 6 and 9 km off‐axis on Segment 2. Plume particle, metal, and CH4 concentrations were all very low, suggesting dilution of hydrothermal fluids by intrusion of seawater into the highly permeable flank area fault zone. The “Onnuri Vent Field” (OVF), located at the summit of OCC‐3‐2, vented clear, low‐temperature fluids supporting abundant vent organisms (21 macrofaunal taxa). The plume particle signal was low to absent, but strong ORP anomalies correlated with high CH4 and low metal concentrations. Sulfide mineralization was present, which suggests both serpentinization and magmatic/lithospheric influence on fluid composition. The detachment fault is the likely pathway for hydrothermal fluid circulation at this off‐axis location. These new vent field discoveries, especially the OVF, contribute valuable information toward understanding Indian Ocean hydrothermal systems and their ecology/biogeography.

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Many countries are trying to reduce their primary energy demand and greenhouse gas (such as carbon dioxide (CO 2 )) emissions. There has been much research on CO 2 utilization to reduce CO 2 emission and increase economic efficiency in industries. In this paper, an integrated optimization strategy of an industrial synthesis gas production plant with additional CO 2 recycling processes using carbon dioxide as a reactant is presented. The CO 2 recycling process allows three different kinds of alternative synthesis gas reaction processes in parallel: steam reforming, dry methane reforming, and reverse water-gas shift reaction. The strategy is based on the integrated superstructure optimization that assists the formulation of the optimal process design problem such that mixed integer programming can be derived. The mathematical programming problem which has flexibility in selecting different synthesis gas reaction processes is used to find the optimal configuration of the process. The industrial synthesis gas plant case studies have been applied to present the optimization strategy. With the optimum configuration, the annualized profit increased by 14% and CO 2 emission decreased by 31% from the base case to the optimal structure. Three other extensions to the optimal design were evaluated for the case studies.

The Cheoeum vent field (CVF) is the first example of an inactive ultramafic-hosted seafloor massive sulphide (SMS) deposit identified in the middle part of the Central Indian Ridge. Here, we report on the detailed mineralogy and geochemistry of ultramafic-hosted sulphide sample atop a chimney, together with a few small fragments. Hydrothermal chimneys are characterised by high concentrations of Au (up to 17.8 ppm) and Sn (up to 1720 ppm). The sulphide mineralisation in the CVF shows (1) early precipitation of anhedral sphalerite and pyrite–marcasite aggregates under relatively low-temperature (< 250 °C) fluid conditions; (2) intensive deposition of subhedral pyrrhotite, isocubanite, chalcopyrite, Fe-rich sphalerite (Sp-III), and electrum from high-temperature (250–365 °C) and reduced fluids in the main mineralisation stage; and (3) a seawater alteration stage distinguished by the mineral assemblage of marcasite pseudomorphs, altered isocubanite phase, covellite, amorphous silica, and Fe-oxyhydroxides. Electrum (< 2 μm in size) is the principal form of Au mineralisation and is mainly associated with the main mineralisation stage. The consistently high fineness of electrum (801 to 909‰) is indicative of the selective saturation of Au over Ag in the fluid during high-temperature mineralisation, which differs from the Au mineralisation associated with typical basaltic-hosted hydrothermal systems on mid-ocean ridges. Tin is mainly substituted in structures of sphalerite, isocubanite, and chalcopyrite as a solid solution, and not as mineral inclusions. The continuously ascending hydrothermal fluids enable the early formed Sn-bearing sulphide to be dissolved and reprecipitated, producing significantly Sn-enriched replacement boundaries between isocubanite and Sp-III. This study suggests that Au–Sn mineralisation could be facilitated by the low redox potential of ultramafic-hosted hydrothermal systems such as in the CVF, which may be a common occurrence along slow-spreading mid-ocean ridges.