Soil organic carbon (SOC) pools are important for maintaining soil productivity and reducing the net CO2 loading of the atmosphere. An 18‐year old long‐term field experiment involving pearl millet‐cluster bean‐castor sequence was conducted on an Entisol in western India to examine the effects of chemical fertilizers and manuring on carbon pools in relation to crop productivity and C sequestration. The data showed that even the addition of 33.5 Mg ha−1 C inputs through crop residues as well as farm yard manure could not compensate the SOC depletion by oxidation and resulted in the net loss of 4.4 Mg C ha−1 in 18 years. The loss of SOC stock in the control was 12 Mg C ha−1. Conjunctive use of chemical fertilizers along with farm yard manure produced higher agronomic yields and reduced the rate of SOC depletion. The higher average seed yields of pearl millet (809 kg ha−1), cluster bean (576), and castor (827) over six cropping seasons were obtained through integrated use of fertilizers and manure. For every Mg increase in profile SOC stock, there was an overall increase of 0.46 Mg of crop yield, comprising increase in individual yield of pearl millet (0.17 Mg ha−1 y−1 Mg−1 SOC), cluster bean (0.14) and castor (0.15). The magnitude of SOC build up was proportional to the C inputs. Carbon pools were significantly correlated with SOC, which increased with application of organic amendments. Threshold C input of 3.3 Mg C ha−1 y−1 was needed to maintain the SOC stock even at the low antecedent level. Copyright © 2011 John Wiley & Sons, Ltd.

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Enricbment of soil organic carbon (SOC) stocks through sequestration of atmospheric CO2 in agricultural soils is important because of its impacts on soil quality, agronomic production, and adaptation to and mitigation of climate change. In a 21-yr field experiment conducted under subbumid tropical conditions in India, the impacts of crop residue C inputs were assessed for the rice (Oryza sativa L.)-lentil (Lens esculenta Moench) cropping sequence. These impacts were evaluated in an experiment involving mineral fertilizers and manuring treatments on crop yield sustainability with reference to critical biomass requirements for maintenance of SOC in an Inceptisol. Application of farmyard manure (FYM) without and with mineral fertilizers increased C input and SOC concentration and stock. In comparison with the control, the 1007<. organic (FYM) treatment had significantly bigher profile SOC (27.5 Mg ha"'), and more C build up (55,0%) and C sequestration (6.6 Mg C ba"') to 1-m depth vis-à-vis the antecedent values in 1986. These parameters were also higher in 100% FYM treatment at a rate providing equivalent amount of tbe recommended dose of N followed by conjunctive use of FYM and mineral fertilizers. The SOC stock and rate of sequestration were positively correlated witb cumulative C input, and with sustainable yield index (SYI) of upland rice and lentil. Higher grain yield (1.95 and 1.04 Mg ha"' of rice and lentil, respectively) was obtained with tbe application of 50% organic (FYM)-i-50% recommended dose of fertilizer (RDF). In comparison, higher SOC sequestration rate was measured witb tbe application of 100% organic (FYM). For every Mg increase in SOC stock in the root zone there was 0.16 and 0.18 Mg ba"'yr"' yield increase of rice and lentil, respectively. For maintaining a stable SOC level (zero change due to cropping), a minimum quantity of 2.47 Mg C ba"' yr"' is required for this soil, climate, cropping system, and fertilization treatments. To achieve this quantity of C, 7.1 Mg of biomass is required to be produced every year vs. average rice and lentil yields of 1.6 and 0.7 Mg ba"', respectively. The sole application of mineral fertilizers at 50 or 100% of the RDF did not maintain the SOC stock. Thus, application of FYM (or other organics) in conjunction with mineral fertilizers is essential to maintaining and enhancing the SOC stock in the rice-based cropping systems.Abbreviations: BD, bulk density; FYM, farmyard manure; INM, integrated nutrient management;NUE, nitrogen use efficiency; RDF, recommended dose of fertilizer; SOC, soil organic carbon; SOM, soil organic matter; SYI, sustainable yield index. R esearch information on rate of enrichment of SOC stocks through .sequestration of atmospheric CO2 in agricultural soils is important because of its impacts on adaptation to and mitigation of climate change, crop productivity, and sustainability. Soil organic matter (SOM) constitutes a signifi-

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Soil carbon (C) pool plays a crucial role in the soil's quality, availability of plant nutrients, environmental functions, and global C cycle. Drylands generally have poor fertility and little organic matter and hence are candidates for C sequestration. Carbon storage in the soil profile not only improves fertility but also abates global warming. Several soils, production, and management factors influence C sequestration, and it is important to identify production and management factors that enhance C sequestrations in dryland soils. The objective of the present study was to examine C stocks at 21 sites under ongoing rainfed production systems and management regimes over the last 25 years on dominant soil types, covering a range of climatic conditions in India. Organic C stocks in the soil profiles across the country showed wide variations and followed the order Vertisols . Inceptisols . Alfisols . Aridisols. Inorganic C and total C stocks were larger in Vertisols than in other soil types. Soil organic C stocks decreased with depth in the profile, whereas inorganic C stocks increased with depth. Among the production systems, soybean-, maize-, and groundnut-based systems showed greater organic C stocks than other production systems. However, the greatest contribution of organic C to total C stock was under upland rice system. Organic C stocks in the surface layer of the soils increased with rainfall (r 5 0.59*), whereas inorganic C stocks in soils were found in the regions with less than 550 mm annual rainfall. Cation exchange capacity had better correlation with organic C stocks than clay content in soils. Results suggest that Indian dryland soils are low in organic C but have potential to sequester. Further potential of tropical soils to sequester more C in soil could be harnessed by 2338 identifying appropriate production systems and management practices for sustainable development and improved livelihoods in the tropics.

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Crop fertilisation with potassium in rainfed agriculture in India is not practised, merely on the assumption that Indian soils are rich in potassium and crops do not need external K supply. However, under continuous cropping in rainfed regions, huge crop K removals are reported, up to 150–200 kg/ha annually, depending upon amount and distribution of rainfall and biomass production. Thus, most of the crops essentially deplete soil K reserves. The present study evaluates the soil K reserves under diverse rainfed production systems and categorises rainfed soils based on different soil K fractions. Depth-wise sampling was done from 21 locations across different soil types under 8 production systems, and various fractions of soil K were determined. Total K was highest in Inceptisols (1.60–2.28%), followed by Aridisols (1.45–1.84%), Vertisols and Vertic sub-groups (0.24–1.72%), and Alfisols and Oxisols (0.30–1.86%), showing a wide variation within each group. Nonexchangeable K reserves were found in a proportionate manner to total K in most of the soil profile. Unlike nonexchangeable K reserves, Vertisols had higher exchangeable K than Inceptisols and Alfisols/Oxisols. Nonexchageable K showed significant positive correlation with total K in Inceptisols and Vertisols, whereas it was non-significant in Alfisols/Oxisosls. However, significant positive correlations were recorded with exchangeable K and nonexchangeable K in all soil types, indicating the dynamic equilibrium between 2 soil K fractions. Nonexchangeable K reserves were included along with exchangeable K in categorising soils into 9 groups for evolving better strategies to manage soil K fertility in rainfed agriculture in India. Finger millet and groundnut crops at Bangalore and Anantapur regions (category I) need immediate attention on K nutrition, as these soils are low in both exchangeable and nonexchangeable K. Similarly, crops grown on soils of S.K. Nagar, Ballowal-Saunkri, and Rakh-Dhiansar, with low exchangeable K and medium nonexchangeable K, would need K fertilisation as these crops (maize and pearlmillet) are K-exhaustive (category II). Pearl millet and upland rice in category III and cotton in category IV need K additions at critical stages. Upland rice in category V needs a maintenance dose of K. In category VI, cereal crops may not need K additions immediately as they have medium exchangeable K and high nonexchangeable K. Long-term sorghum cropping may need K supply after few years (category VII). Soils in category VIII are adequate in nonexchangeable K and medium exchangeable K and the crops, groundnut, cotton, sorghum, and soybean, may not need external K immediately. For soils in category IX, K fertilisation is not required to the crops (sorghum and soybean) as these soils have high exchangeable and nonexchangeable K.

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