Exposure to volatile organic compounds (VOCs) is widely associated with adverse health effects.Detection and monitoring of VOCs are important for maintaining safe and healthy industrial and domestic environments. Interferometry is a highly-sensitive optical measurement technique that has been widely applied to a vast range of physical parameters from the speed of light to temperature and has also been used to detect VOCs at the sub-ppm range. Owing to the vast range of interferometer arrangements and processing techniques, this review assesses the different approaches adopted in detecting VOCs. Different interferometry arrangements including the Fabry-Perot interferometry, Sagnac interferometry and Mach-Zehnder interferometry are reviewed for VOC detection, including the different sensing films and materials employed. We present the basis of each technique, applications and limitations. The different interferometry techniques are summarized by comparing the sensitivity, limit of detection, linearity, response time and the challenges of current interferometry techniques.Lastly, prospects to realize a miniaturized, high-sensitive and multiplex interferometric sensors based on the recent technology are suggested.
Several gas molecules of environmental and domestic significance exhibit a strong deep-UV absorption. Therefore, a sensitive and a selective gas detector based on this unique molecular property (i.e., absorption at a specific wavelength) can be developed using deep-UV absorption spectrophotometry. UV absorption spectrometry provides a highly sensitive, reliable, self-referenced, and selective approach for gas sensing. This review article addresses the recent progress in the application of deep-UV absorption for gas sensing owing to its inherent features and tremendous potentials. Applications, advancements, and challenges related to UV emission sources, gas cells, and UV photodetectors are assessed and compared. We present the relevant theoretical aspects and challenges associated with the development of portable sensitive spectrophotometer. Finally, the applications of UV absorption spectrometry for ozone, NO2, SO2, and aromatic organic compounds during the last decades are discussed and compared. A portable UV absorption spectrophotometer can be developed by using LEDs, hollow core waveguides (HCW), and UV photodetectors (i.e., photodiodes). LED provides a portable UV emission source with low power input, low-intensity drifts, low cost, and ease of alignment. It is a quasi-chromatic UV source and covers the absorption band of molecules without optical filters for absorbance measurement of a target analyte. HCWs can be applied as a miniature gas cell for guiding UV radiation for measurement of low gas concentrations. Photodiodes, on the other hand, offer a portable UV photodetector with excellent spectral selectivity with visible rejection, minimal dark current, linearity, and resistance against UV-aging.
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