Battery industries and research groups are further investigating LiCoO2 to unravel the capacity at high‐voltages (>4.3 vs Li). The research trends are towards the surface modification of the LiCoO2 and stabilize it structurally and chemically. In this report, the recent progress in the surface‐coating materials i.e., single‐element, binary, and ternary hybrid‐materials etc. and their coating methods are illustrated. Further, the importance of evaluating the surface‐coated LiCoO2 in the Li‐ion full‐cell is highlighted with our recent results. Mg,P‐coated LiCoO2 full‐cells exhibit excellent thermal stability, high‐temperature cycle and room‐temperature rate capabilities with high energy‐density of ≈1.4 W h cc−1 at 10 C and 4.35 V. Besides, pouch‐type full‐cells with high‐loading (18 mg cm−2) electrodes of layered‐Li(Ni,Mn)O2 ‐coated LiCoO2 not only deliver prolonged cycle‐life at room and elevated‐temperatures but also high energy‐density of ≈2 W h cc−1 after 100 cycles at 25 °C and 4.47 V (vs natural graphite). The post‐mortem analyses and experimental results suggest enhanced electrochemical performances are attributed to the mechanistic behaviour of hybrid surface‐coating layers that can mitigate undesirable side reactions and micro‐crack formations on the surface of LiCoO2 at the adverse conditions. Hence, the surface‐engineering of electrode materials could be a viable path to achieve the high‐energy Li‐ion cells for future applications.
Sodium-ion batteries are the next-generation in battery technology; however, their commercial development is hampered by electrode performance. The P2-type Na 2/3 (Fe 1/2 Mn 1/2 )O 2 with a hexagonal structure and P6 3 /mmc space group is considered a candidate sodium-ion battery cathode material due to its high capacity (~ 190 mAh.g -1 ) and energy density (~ 520 mWh.g -1 ), which are comparable to the commercial LiFePO 4 and LiMn 2 O 4 lithium-ion battery cathodes, with previously-unexplained poor cycling performance being the major barrier to its commercial application. We use operando synchrotron X-ray powder diffraction to understand the origins of the capacity fade of the Na 2/3 (Fe 1/2 Mn 1/2 )O 2 material during cycling over the relatively-wide 1.5 -4.2 V (vs. Na) window. We found a complex phase-evolution, involving transitions from P6 3 /mmc (P2-type at the open-circuit voltage) -P6 3 (OP4-type when fully-charged) -P6 3 /mmc (P2-type at 3.4 -2.0 V) -Cmcm (P2-type at 2.0 -1.5 V) symmetry structures during the desodiation and sodiation of the Na 2/3 (Fe 1/2 Mn 1/2 )O 2 cathode. The associated large cell-volume changes with the multiple two-phase reactions are likely to be responsible for the poor cycling performance, clearly suggesting to a 2.0 -4.0 V window of operation as a strategy to improve cycling performance. We demonstrated here that the P2-type Na 2/3 (Fe 1/2 Mn 1/2 )O 2 cathode is able to deliver ~25% better cycling performance with the strategic operation window. This significant improvement in cycling performance implies that by characterizing the phase evolution and reaction mechanisms during battery function we are able to propose these modifications to the conditions of battery use that improve performance, highlighting the importance of the interplay between structure and electrochemistry.
Cathode material degradation during cycling is one of the key obstacles to upgrading lithium-ion and beyond-lithium-ion batteries for high-energy and varied-temperature applications. Herein, we highlight recent progress in material surface-coating as the foremost solution to resist the surface phase-transitions and cracking in cathode particles in mono-valent (Li, Na, K) and multi-valent (Mg, Ca, Al) ion batteries under high-voltage and varied-temperature conditions. Importantly, we shed light on the future of materials surface-coating technology with possible research directions. In this regard, we provide our viewpoint on a novel hybrid surface-coating strategy, which has been successfully evaluated in LiCoO -based-Li-ion cells under adverse conditions with industrial specifications for customer-demanding applications. The proposed coating strategy includes a first surface-coating of the as-prepared cathode powders (by sol-gel) and then an ultra-thin ceramic-oxide coating on their electrodes (by atomic-layer deposition). What makes it appealing for industry applications is that such a coating strategy can effectively maintain the integrity of materials under electro-mechanical stress, at the cathode particle and electrode- levels. Furthermore, it leads to improved energy-density and voltage retention at 4.55 V and 45 °C with highly loaded electrodes (≈24 mg.cm ). Finally, the development of this coating technology for beyond-lithium-ion batteries could be a major research challenge, but one that is viable.
Sodium-ion batteries can be the best
alternative to lithium-ion batteries, because of their similar electrochemistry,
nontoxicity, and elemental abundance and the low cost of sodium. They
still stand in need of better cathodes in terms of their structural
and electrochemical aspects. Accordingly, the present study reports
the first example of the preparation of Na2/3(Fe1/2Mn1/2)O2 hierarchical nanofibers by electrospinning.
The nanofibers with aggregated nanocrystallites along the fiber direction
have been characterized structurally and electrochemically, resulting
in enhanced cyclability when compared to nanoparticles, with initial
discharge capacity of ∼195 mAh g–1. This
is attributed to the good interconnection among the fibers, with well-guided
charge transfers and better electrolyte contacts.
Developing nano/micro-structures which can effectively upgrade the intriguing
properties of electrode materials for energy storage devices is always a key
research topic. Ultrathin nanosheets were proved to be one of the potential
nanostructures due to their high specific surface area, good active contact areas
and porous channels. Herein, we report a unique hierarchical micro-spherical
morphology of well-stacked and completely miscible molybdenum disulfide
(MoS2) nanosheets and graphene sheets, were successfully synthesized
via a simple and industrial scale spray-drying technique to take the advantages of
both MoS2 and graphene in terms of their high practical capacity values
and high electronic conductivity, respectively. Computational studies were performed
to understand the interfacial behaviour of MoS2 and graphene, which
proves high stability of the composite with high interfacial binding energy
(−2.02 eV) among them. Further, the lithium and sodium
storage properties have been tested and reveal excellent cyclic stability over 250
and 500 cycles, respectively, with the highest initial capacity values of
1300 mAh g−1 and 640 mAh
g−1 at 0.1 A
g−1.
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