Specific heat, resistivity, magnetic susceptibility, linear thermal expansion (LTE), and highresolution synchrotron X-ray powder diffraction investigations of single crystals Fe1+yTe (0.06 ≤ y ≤ 0.15) reveal a splitting of a single, first-order transition for y ≤ 0.11 into two transitions for y ≥ 0.13. Most strikingly, all measurements on identical samples Fe1.13Te consistently indicate that, upon cooling, the magnetic transition at TN precedes the first-order structural transition at a lower temperature Ts. The structural transition in turn coincides with a change in the character of the magnetic structure. The LTE measurements along the crystallographic c-axis displays a small distortion close to TN due to a lattice striction as a consequence of magnetic ordering, and a much larger change at Ts. The lattice symmetry changes, however, only below Ts as indicated by powder X-ray diffraction. This behavior is in stark contrast to the sequence in which the phase transitions occur in Fe pnictides.
Variable temperature scanning tunneling microscopy/spectroscopy studies on single crystals and epitaxial thin films of hole-doped manganites, which show colossal magnetoresistance, have been done. We have investigated the variation of the density of states, at and near the Fermi energy (E f ), as a function of temperature. Simple calculations have been carried out, to find out the effect of temperature on the tunneling spectra and extract the variation of density of states with temperature, from the observed data. We also report here, atomic resolution images, on the single crystals and larger range images showing the growth patterns on thin films. Our investigation shows unambiguously that there is a rapid variation in density of states for temperatures near the Curie temperature (Tc). While for temperatures below Tc, a finite DOS is observed at E f , for temperatures near Tc a hard gap opens up in the density of states near E f . For temperatures much higher than Tc, this gap most likely gives way to a soft gap. The observed hard gap for temperatures near Tc, is somewhat higher than the transport gap for all the materials. For different materials, we find that the magnitude of the hard gap decreases as the Tc of the material increases and eventually, for materials with a Tc close to 400 K, the value of the gap approaches zero. PACS
The floating-zone method with different growth ambiences has been used to selectively obtain hexagonal or orthorhombic DyMnO(3) single crystals. The crystals were characterized by x-ray powder diffraction of ground specimens and a structure refinement as well as electron diffraction. We report magnetic susceptibility, magnetization and specific heat studies of this multiferroic compound in both the hexagonal and the orthorhombic structure. The hexagonal DyMnO(3) shows magnetic ordering of Mn(3+) (S = 2) spins on a triangular Mn lattice at T(N)(Mn) = 57 K characterized by a cusp in the specific heat. This transition is not apparent in the magnetic susceptibility due to the frustration on the Mn triangular lattice and the dominating paramagnetic susceptibility of the Dy(3+) (S = 9/2) spins. At T(N)(Dy) = 3 K, a partial antiferromagnetic order of Dy moments has been observed. In comparison, the magnetic data for orthorhombic DyMnO(3) display three transitions. The data broadly agree with results from earlier neutron diffraction experiments, which allows for the following assignment: a transition from an incommensurate antiferromagnetic ordering of Mn(3+) spins at T(N)(Mn) = 39 K, a lock-in transition at T(lock-in) = 16 K and a second antiferromagnetic transition at T(N)(Dy) = 5 K due to the ordering of Dy moments. Both the hexagonal and the orthorhombic crystals show magnetic anisotropy and complex magnetic properties due to 4f-4f and 4f-3d couplings.
Articles you may be interested inEnhanced magnetism and ferroelectricity in epitaxial Pb(Zr0.52Ti0.48)O3/CoFe2O4/La0.7Sr0.3MnO3 multiferroic heterostructures grown using dual-laser ablation technique J. Appl. Phys. 115, 17D707 (2014) Antisite disorder is observed to have significant impact on the magnetic properties of the double perovskite Y 2 CoMnO 6 which has been recently identified as a multiferroic. A paramagneticferromagnetic phase transition occurs in this material at T c % 75 K. At 2 K, it displays a strong ferromagnetic hysteresis with a significant coercive field of H c % 15 kOe. Sharp steps are observed in the hysteresis curves recorded below 8 K. In the temperature range 2 K T 5 K, the hysteresis loops are anomalous as the virgin curve lies outside the main loop. The field-cooling conditions as well as the rate of field-sweep are found to influence the steps. Quantitative analysis of the neutron diffraction data shows that at room temperature, Y 2 CoMnO 6 consists of 62% of monoclinic P2 1 /n with nearly 70% antisite disorder and 38% Pnma. The bond valence sums indicate the presence of other valence states for Co and Mn which arise from disorder. We explain the origin of steps by using a model for pinning of magnetization at the antiphase boundaries created by antisite disorder. The steps in magnetization closely resemble the martensitic transformations found in intermetallics and display first-order characteristics as revealed in the Arrott's plots. V C 2014 AIP Publishing LLC.
Slow intrinsic fluctuations of resistance, also known as the flicker noise or 1/f-noise, in the surface transport of strong topological insulators (TIs) is a poorly understood phenomenon. Here, we have systematically explored the 1/f-noise in field-effect transistors (FET) of mechanically exfoliated Bi1.6Sb0.4Te2Se TI films when transport occurs predominantly via the surface states. We find that the slow kinetics of the charge disorder within the bulk of the TI induces mobility fluctuations at the surface, providing a new source of intrinsic 1/f-noise that is unique to bulk TI systems. At small channel thickness, the noise magnitude can be extremely small, corresponding to the phenomenological Hooge parameter γH as low as ≈10(-4), but it increases rapidly when channel thickness exceeds ∼1 μm. From the temperature (T)-dependence of noise, which displayed sharp peaks at characteristic values of T, we identified generation-recombination processes from interband transitions within the TI bulk as the dominant source of the mobility fluctuations in surface transport. Our experiment not only establishes an intrinsic microscopic origin of noise in TI surface channels, but also reveals a unique spectroscopic information on the impurity bands that can be useful in bulk TI systems in general.
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