Highly luminescent glass-stabilized CsPbX3 (X = Cl, Br, I) perovskite QDs are fabricated via an in situ glass crystallization strategy and fluorine doping.
Currently,
it is of great challenge to achieve cation exchange in CsPbX3 (X = Cl, Br, I) perovskite nanocrystals (NCs) on account of rigid
Pb2+ octahedral coordination protected by six halogen anions
(PbX6
4–). Herein, we demonstrate that
dynamic halogen exchange can effectively open up PbX6
4– octahedrons and enable fast Mn-to-Pb cation exchange
at room temperature in a few seconds. Importantly, Cl concentration
rather than Mn one is demonstrated to be a dominant factor for cation
exchange, where different Mn2+/Cl– salts
can be adopted as Mn/Cl sources and Cl-to-Cl or Cl-to-Br anion exchange
is the necessary prerequisite. Such a facile synthesizing method can
lead to the feasibility of tuning emissive colors for the Mn-doped
CsPb(Cl/Br)3 NCs by controlling both cation and anion exchanges
and open a new way to replace Pb2+ in CsPbX3 NCs by other nontoxic metal elements.
With admirable luminescence performance and a cheap price, non-rare-earth-based oxide red phosphors are a potential competitor of rare-earth-doped phosphors for warm white LEDs (WLEDs). Herein, a novel double-perovskite Ba2GdSbO6:Mn4+ phosphor, demonstrating strong red emission ascribed to a spin-forbidden Mn4+:2Eg → 4A2g transition in the region of 620-750 nm, has been synthesized via a solid-state reaction route. The microstructure and luminescence properties are investigated in detail. The concentration quenching mechanism and thermal stability based on thermal quenching characteristics are also discussed. Importantly, Li+, Mg2+, Zn2+, Si4+, Ti4+ and Ge4+ dopants are discovered to be beneficial for enhancing Mn4+ luminescence, and the related mechanisms are comprehensively described. In addition, by combining red-emitting Ba2GdSb0.994O6:0.003Mn4+,0.003Mg2+ with the commercial blue-emitting BaMgAl10O17:Eu2+ and green-emitting Ba3La6(SiO4)6:Eu2+ phosphors in various ratios, a series of WLED devices with a tunable correlated color temperature (CCT) evolving from 6256 to 3486 K and a color rendering index (CRI) increasing from 72.1 to 88.3 are achieved.
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