Articles you may be interested inResonant vibration-vibration energy transfer between highly vibrationally excited O2(X 3Σ− g ,v=15-26) and CO2, N2O, N2, and O3Temperature dependence of nearresonant vibrational energy transfer between CO2 and deuterated methanes J. Chem. Phys. 79, 2212 (1983); 10.1063/1.446070
Laser double resonance measurements of vibrational energy transfer rates and mechanisms in HF(v = 2)The rate of the resonant vibration-vibration energy-transfer process between mode va of CO 2 and N2 has been measured from 450 o -2600 o K by monitoring the infrared emission from mode Va at 4.26 p. behind incident shocks in CO2-N2 gas mixtures. The data are shown to be in agreement with recent laser fluorescent measurements from 300 o -1000 o K. The combined data for the probability per collision are compared to theoretical calculations and indicate that below 10000K the interaction is dominated by long-range forces and a probability inversely proportional to temperature is obtained, while above lOOOoK the probability increases with temperature and the interaction is due to short-range forces.
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