New internal coordinate gradients, s-vectors, are derived using geometric algebra. The internal coordinates are based on a completely general description of the molecular geometry in terms of internal vectors. The internal coordinate gradients allow kinetic energy operators to be easily expressed in terms of orthogonal or non-orthogonal coordinate systems. Using this approach, a new exact vibrational kinetic energy operator for centrally-connected penta-atomic systems is derived for an internal polyspherical coordinate system based on orthogonal internal vectors. Difficulties associated with the well known coordinate redundancy in centrally-connected penta-atomic systems are discussed and overcome.

New analytical bending and stretching, ground electronic state, potential energy surfaces for CH(3)F are reported. The surfaces are expressed in bond-length, bond-angle internal coordinates. The four-dimensional stretching surface is an accurate, least squares fit to over 2000 symmetrically unique ab initio points calculated at the CCSD(T) level. Similarly, the five-dimensional bending surface is a fit to over 1200 symmetrically unique ab initio points. This is an important first stage towards a full nine-dimensional potential energy surface for the prototype CH(3)F molecule. Using these surfaces, highly excited stretching and (separately) bending vibrational energy levels of CH(3)F are calculated variationally using a finite basis representation method. The method uses the exact vibrational kinetic energy operator derived for XY(3)Z systems by Manson and Law (preceding paper, Part I, Phys. Chem. Chem. Phys., 2006, 8, DOI: 10.1039/b603106d). We use the full C(3v) symmetry and the computer codes are designed to use an arbitrary potential energy function. Ultimately, these results will be used to design a compact basis for fully coupled stretch-bend calculations of the vibrational energy levels of the CH(3)F system.