The possibility of
actively controlling structural colors has recently
attracted a lot of attention, in particular for new types of reflective
displays (electronic paper). However, it has proven challenging to
achieve good image quality in such devices, mainly because many subpixels
are necessary and the semitransparent counter electrodes lower the
total reflectance. Here we present an inorganic electrochromic nanostructure
based on tungsten trioxide, gold, and a thin platinum mirror. The
platinum reflector provides a wide color range and makes it possible
to “reverse” the device design so that electrolyte and
counter electrode can be placed behind the nanostructures with respect
to the viewer. Importantly, this makes it possible to maintain high
reflectance regardless of how the electrochemical cell is constructed.
We show that our nanostructures clearly outperform the latest commercial
color e-reader in terms of both color range and brightness.
Precise manipulation of light–matter interactions has enabled a wide variety of approaches to create bright and vivid structural colors. Techniques utilizing photonic crystals, Fabry–Pérot cavities, plasmonics, or high‐refractive‐index dielectric metasurfaces have been studied for applications ranging from optical coatings to reflective displays. However, complicated fabrication procedures for sub‐wavelength nanostructures, limited active areas, and inherent absence of tunability of these approaches impede their further development toward flexible, large‐scale, and switchable devices compatible with facile and cost‐effective production. Here, a novel method is presented to generate structural color images based on monochromic conducting polymer films prepared on metallic surfaces via vapor phase polymerization and ultraviolet (UV) light patterning. Varying the UV dose enables synergistic control of both nanoscale film thickness and polymer permittivity, which generates controllable structural colors from violet to red. Together with grayscale photomasks this enables facile fabrication of high‐resolution structural color images. Dynamic tuning of colored surfaces and images via electrochemical modulation of the polymer redox state is further demonstrated. The simple structure, facile fabrication, wide color gamut, and dynamic color tuning make this concept competitive for applications like multifunctional displays.
Dynamic control of structural colors across the visible spectrum with high brightness has proven to be a difficult challenge. Here, this is addressed with a tuneable reflective nano‐optical cavity that uses an electroactive conducting polymer (poly(thieno[3,4‐b]thiophene)) as spacer layer. Electrochemical doping and dedoping of the polymer spacer layer provides reversible tuning of the cavity's structural color throughout the entire visible range and beyond. Furthermore, the cavity provides high peak reflectance that varies only slightly between the reduced and oxidized states of the polymer. The results indicate that the polymer undergoes large reversible thickness changes upon redox tuning, aided by changes in optical properties and low visible absorption. The electroactive cavity concept may find particular use in reflective displays, by opening for tuneable monopixels that eliminate limitations in brightness of traditional subpixel‐based systems.
Certain bird species
have evolved spectacular colors that arise
from organized nanostructures of melanin. Its high refractive index
(∼1.8) and broadband absorptive properties enable vivid structural
colors that are nonsusceptible to photobleaching. Mimicking natural
melanin structural coloration could enable several important applications,
in particular, for noniridescent systems with colors that are independent
of incidence angle. Here, we address this by forming melanin photonic
crystal microdomes by inkjet printing. Owing to their curved nature,
the microdomes exhibit noniridescent vivid structural coloration,
tunable throughout the visible range via the size of the nanoparticles.
Large-area arrays (>1 cm
2
) of high-quality photonic
microdomes
could be printed on both rigid and flexible substrates. Combined with
scalable fabrication and the nontoxicity of melanin, the presented
photonic microdomes with noniridescent structural coloration may find
use in a variety of applications, including sensing, displays, and
anticounterfeit holograms.
Surface Plasmon Resonance (SPR)-based sensors have the advantage of being label-free, enzyme-free and real-time. However, their spreading in multidisciplinary research is still mostly limited to prism-coupled devices. Plasmonic gratings, combined with a simple and cost-effective instrumentation, have been poorly developed compared to prism-coupled system mainly due to their lower sensitivity. Here we describe the optimization and signal enhancement of a sensing platform based on phase-interrogation method, which entails the exploitation of a nanostructured sensor. This technique is particularly suitable for integration of the plasmonic sensor in a lab-on-a-chip platform and can be used in a microfluidic chamber to ease the sensing procedures and limit the injected volume. The careful optimization of most suitable experimental parameters by numerical simulations leads to a 30–50% enhancement of SPR response, opening new possibilities for applications in the biomedical research field while maintaining the ease and versatility of the configuration.
Plasmonic metasurfaces based on ensembles of distributed metallic nanostructures can absorb, scatter and in other ways shape light at the nanoscale. Forming hybrid plasmonic metasurfaces by combination with other materials opens up for new research directions and novel applications. This perspective highlights some of the recent advancements in this vibrant research field. Particular emphasis is put on hybrid plasmonic metasurfaces comprising organic materials and on concepts related to switchable surfaces, light-to-heat conversion, and hybridized light-matter states based on strong coupling.
Structural Color Images
In article number 2102451, Magnus P. Jonsson and co‐workers demonstrate a new approach to produce dynamic structural colors with UV‐patterned conducting polymers. The UV patterning controls the film thickness and polymer permittivity, and enables production of multicolor images with a single exposure step. Combined with the electrochemical tunability of the conducting polymer, these devices hold promise for next‐generation multifunctional displays.
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