Porous alkali activated materials (AAM), can be obtained from waste glass powder and slag mixtures by alkali activation with NaOH solution. To obtain an adequate porous microstructure, the hardened AAM pastes were thermally treated at temperatures ranging between 900°C and 1000°C, for 60 or 30 minutes. Due to the intumescent behaviour specific for this type of materials, an important increase of the volume and porosity occurs during the thermal treatment.
The partial substitution of waste glass powder with slag, determines the increase of compressive strength assessed before (up to 37 MPa) and after (around 10 MPa) thermal treatment; the increase of slag dosage also determines the increase of the activation temperature of the intumescent process (above 950°C).
The high porosity and the specific microstructure (closed pores with various shapes and sizes) of these materials recommend them to be utilised as thermal and acoustical insulation materials.
The electric field dependence of the dielectric constant (dc-tunability) as a function of temperature for a few compositions of Ba(Sn,Ti)O3 ceramics was investigated. Dense and homogeneous BaSnxTi1−xO3 ceramics (ferroelectric for x = 0.05 and x = 0.10, relaxor for x = 0.15 and 0.20) with high dielectric constant and low dielectric losses were prepared by solid state reaction. Their dc-tunability characteristics were investigated at a few temperatures from 20–120 °C, including the Curie range. The tunability data were discussed in terms of the Johnson model completed with a Langevin term that describes the “extrinsic” contribution to the nonlinear ɛ(E) dependences.
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