We propose to use optical tweezers to probe the Casimir interaction between microspheres inside a liquid medium for geometric aspect ratios far beyond the validity of the widely employed proximity force approximation. This setup has the potential for revealing unprecedented features associated to the non-trivial role of the spherical curvatures. For a proof of concept, we measure femtonewton double layer forces between polystyrene microspheres at distances above 400 nm by employing very soft optical tweezers, with stiffness of the order of fractions of a fN/nm. As a future application, we propose to tune the Casimir interaction between a metallic and a polystyrene microsphere in saline solution from attraction to repulsion by varying the salt concentration. With those materials, the screened Casimir interaction may have a larger magnitude than the unscreened one. This line of investigation has the potential for bringing together different fields including classical and quantum optics, statistical physics and colloid science, while paving the way for novel quantitative applications of optical tweezers in cell and molecular biology.

Negative values of the Casimir entropy occur quite frequently at low temperatures in arrangements of metallic objects. The physical reason lies either in the dissipative nature of the metals as is the case for the plane-plane geometry or in the geometric form of the objects involved. Examples for the latter are the sphere-plane and the sphere-sphere geometry, where negative Casimir entropies can occur already for perfect metal objects. After appropriately scaling out the size of the objects, negative Casimir entropies of geometric origin are particularly pronounced in the limit of large distances between the objects. We analyze this limit in terms of the different scattering channels and demonstrate how the negativity of the Casimir entropy is related to the polarization mixing arising in the scattering process. If all involved objects have a finite zero-frequency conductivity, the channels involving transverse electric modes are suppressed and the Casimir entropy within the large-distance limit is found to be positive.

Dissipative electromagnetic response and scattering geometry are potential sources for the appearance of a negative Casimir entropy. We show that the dissipative contribution familiar from the plane-plane geometry appears also in the plane-sphere and the sphere-sphere geometries and adds to the negative Casimir entropy known to exist in these geometries even for perfectly reflecting objects. Taking the sphere-sphere geometry as an example, we carry out a scattering-channel analysis, which allows us to distinguish between the contributions of different polarizations. We demonstrate that dissipation and geometry share a common feature making possible negative values of the Casimir entropy. In both cases there exists a scattering channel whose contribution to the Casimir free energy vanishes in the high-temperature limit. While the mode-mixing channel is associated with the geometric origin, the transverse electric channel is associated with the dissipative origin of the negative Casimir entropy. By going beyond the Rayleigh limit, we find even for large distances that negative Casimir entropies can occur also for Drude-type metals provided the dissipation strength is sufficiently small.

In an almost cubical reactor 90 l in volume which is intended to deposit organic polymers by plasma-enhanced chemical vapor deposition (PECVD), microwave power is coupled into the volume via a quartz window which extends to approximately 1/10 of the sidewall area. Since the plasma is excited locally, plasma parameters like electron temperature and plasma density are expected to exhibit a spatial variation. The compilation of these plasma quantities has been accomplished with a bendable single Langmuir probe. To isolate the tungsten wire against its grounded housing tube, it was coated with polyparylene. After having compared this construction with our Langmuir probe, which has been now in use for more than a decade, we have taken data of more than half the volume of the reactor with argon and have found a definitive radial inhomogenity for all plasma parameters. To investigate whether this conduct can be determined applying optical emission spectroscopy, we improved our spectrometer which had been used for endpoint detection purposes and plasma diagnostics in chlorine-containing ambients where we could detect also a spatial dependence. This behavior is discussed in terms of Lieberman's global model.

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