Abstract. In order to estimate past changes in atmospheric NOx concentration, nitrate, an oxidation product of NOx, has often been measured in polar ice cores. In the frame of the European Project for

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The very successful application of a CFA (Continuous flow analysis) system in the GRIP project (Greenland Ice Core Project) for high-resolution ammonium, calcium, hydrogen peroxide, and formaldehyde measurements along a deep ice core led to further development of this analysis technique. We included methods for continuous analysis of sodium, nitrate, sulfate, and electrolytical conductivity, while the existing methods have been improved. The melting device has been optimized to allow the simultaneous analysis of eight components. Furthermore, a new melter was developed for analyzing firn cores. The system has been used in the frame of the European Project for Ice Coring in Antarctica (EPICA) for in-situ analysis of several firn cores from Dronning Maud Land, Antarctica, and for the new ice core drilled at Dome C, Antarctica.

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The possibility to adapt chemometrics approaches for the quantitative estimation of heavy metals in soils polluted by a mining accident was explored. In April 1998, the dam of a mine tailings pond in Aznalcóllar (Spain) collapsed and flooded an area of more than 4000 ha with pyritic sludge contaminated with high concentrations of heavy metals. Six months after the end of the first remediation campaign, soil samples were collected for chemical analysis and measurement of visible to near-infrared reflectance (0.35-2.4 microm). Concentrations for As, Cd, Cu, Fe, Hg, Pb, S, Sb, and Zn were well above background values. Prediction of heavy metals was achieved by stepwise multiple linear regression analysis (MLR) and an artificial neural network (ANN) approach. It was possible to predict six out of nine elements with high accuracy. Best R2 between predicted and chemically analyzed concentrations were As, 0.84; Fe, 0.72; Hg, 0.96; Pb, 0.95; S, 0.87; and Sb, 0.93. Results for Cd (0.51), Cu (0.43), and Zn (0.24) were not significant. MLR and ANN both achieved similar results. Correlation analysis revealed that most wavelengths important for prediction could be attributed to absorptions features of iron and iron oxides. These results indicate that it is feasible to predict heavy metals in soils contaminated by mining residuals using the rapid and cost-effective reflectance spectroscopy.

In this article, we evaluate the performance of a commercially available lifetime-based optode and compare it with data obtained by other methods. We performed a set of 10 different tests, including targeted laboratory evaluations and field studies, covering a wide range of situations from shallow coastal waters and wastewater treatment plants to abyssal depths. Our principal conclusion is that, owing to high accuracy (± 2 µM), long-term stability (more than 20 months), lack of pressure hysteresis, and limited cross-sensitivity, this method is overall more suitable for oxygen monitoring than other methods.

Large amounts of the greenhouse gas methane are released from the seabed to the water column 1 where it may be consumed by aerobic methanotrophic bacteria 2. This microbial filter is consequently the last marine sink for methane before its liberation to the atmosphere. The size and activity of methanotrophic communities, which determine the capacity of the water column methane filter, are thought to be mainly controlled by nutrient and redox dynamics 3-7 , but little is known about the effects of ocean currents. Here we show that cold bottom water at methane seeps west off Svalbard, containing a large number of aerobic methanotrophs, was rapidly displaced by warmer water with a considerably smaller methanotrophic community. This water mass exchange, caused by short-term variations of the West Spitsbergen Current, constitutes an oceanographic switch severely reducing methanotrophic activity in the water column. Strong and fluctuating currents are widespread oceanographic features common at many methane seep systems and are thus likely to globally affect methane oxidation in the ocean water column. Large amounts of methane are stored in the subsurface of continental margins as solid gas hydrates, gaseous reservoirs or dissolved in pore water 8. At cold seeps, various physical, chemical, and geological processes force subsurface methane to ascend along pathways of structural weakness to the sea floor where a portion of this methane is utilised by anaerobic and aerobic methanotrophic microbes 1,9. On a global scale, about 0.02 Gt yr-1 (3-3.5% of the atmospheric budget 10) of methane bypasses the benthic filter system and is liberated to the ocean water column 1 where some of it is oxidised aerobically (aerobic oxidation of methane-MOx) (ref 2), or less commonly where the water column is anoxic, anaerobically (anaerobic oxidation of methane-AOM) (refs 2, 11). MOx is performed by methanotrophic bacteria (MOB) typically belonging to the Gamma-(type I) or Alphaproteobacteria (type II) (refs 12, 13): CH 4 + 2 O 2 → CO 2 + 2 H 2 O Water column MOx is consequently the final sink for methane before its release to the atmosphere, where it acts as a potent greenhouse gas. The water column MOx filter could become more

Abstract. Carbon cycling in Peruvian margin sediments (11 and 12° S) was examined at 16 stations, from 74 m water depth on the middle shelf down to 1024 m, using a combination of in situ flux measurements, sedimentary geochemistry and modelling. Bottom water oxygen was below detection limit down to ca. 400 m and increased to 53 μM at the deepest station. Sediment accumulation rates decreased sharply seaward of the middle shelf and subsequently increased at the deep stations. The organic carbon burial efficiency (CBE) was unusually low on the middle shelf (<20%) when compared to an existing global database, for reasons which may be linked to episodic ventilation of the bottom waters by oceanographic anomalies. Deposition of reworked, degraded material originating from sites higher up on the slope is proposed to explain unusually high sedimentation rates and CBE (>60%) at the deep oxygenated sites. In line with other studies, CBE was elevated under oxygen-deficient waters in the mid-water oxygen minimum zone. Organic carbon rain rates calculated from the benthic fluxes alluded to efficient mineralisation of organic matter in the water column compared to other oxygen-deficient environments. The observations at the Peruvian margin suggest that a lack of oxygen does not greatly affect the degradation of organic matter in the water column but promotes the preservation of organic matter in sediments.