This contribution demonstrates and discusses electrically tunable polymer planar Bragg gratings based on bulk cyclic olefin copolymers. A lithographic single‐writing‐step method and femtosecond laser reductive sintering of copper(II) oxide nanoparticles are subsequently employed in order to generate buried photonic structures and copper conducting paths on top of the polymer substrate. This way, the necessary number of process steps for fabricating a planar polymer‐based electro‐optical device is greatly reduced. The response of a fully electrified grating structure follows temperature changes, induced by the copper conducting path, with sensitivities up to −31 pm K−1. Dilatometric measurements show that the specimen's behavior is correlated to the situationally reduced thermal expansion of the bulk polymer substrate. In consequence, the tuning response of the photonic platform follows a second order polynomial, whereas a direct current of 30 mA, which correlates to a power consumption of 18.3 mW, leads to a local temperature increase and a residual Bragg wavelength shift of 19.6 K and −547 pm, respectively. Moreover, the outstanding flexibility of the proposed fabrication concept is underlined by demonstrating alternative conducting path geometries, whereas one of the additional designs is adapted to control the spectral width of the Bragg grating's reflection peak.
This Letter demonstrates a novel, to the best of our knowledge, hydrogen sensor based on a polymer planar Bragg grating coated with Pt-loaded
W
O
3
-
S
i
O
2
. The reflected Bragg signal shows a distinct peak splitting correlated to substrate anisotropies originating from the injection molding process. Especially at low
H
2
concentrations, both sensing peaks exhibit an outstanding response to the heat generated by the exothermic reaction between hydrogen molecules and coating. Thereby, a hydrogen volume ratio of 50 ppm leads to a Bragg wavelength shift of
−
37
p
m
, which yields an outstandingly low detection limit of only 5 ppm
H
2
in air. Thus, functionalized polymer planar Bragg gratings are eminently suitable for
H
2
leak detection applications.
We report on a femtosecond laser based fabrication technique that enables simultaneous single-step generation of optical waveguides and Bragg gratings inside bulk cyclic olefin copolymers. Due to the nonlinear absorption of focused and spatially modulated laser radiation with a wavelength of 514 nm and a pulse duration of 450 fs, a modification concluding a refractive index shift increase inside the substrate can be achieved. A sophisticated characterization of the generated waveguides by means of an elaborate cut-back method reveals a maximum attenuation of 3.2 dB/cm. Additionally, a Mach-Zehnder interferometer is used to examine the waveguide’s refractive index profile. The integrated Bragg grating structures exhibit reflectivities up to 95 % and a spectral full width at half maximum of 288 pm, at a Bragg wavelength of 1582 nm, whereas the grating period can be deliberately chosen by adapting the fabrication parameters. Thus, due to its increased flexibility and the resulting dispensability of cost-intensive phase masks, this method constitutes an especially promising fabrication process for polymer Bragg gratings inside of bulk materials.
In this Letter, we demonstrate a high-temperature stable polymer planar waveguide Bragg grating based on cyclo-olefin copolymers. The high glass transition temperature of the polymer material amounting to 178°C, in conjunction with a high-temperature stable UV-curable adhesive used to connect the polymer sensor to a standard single-mode fiber, enables temperature readings of up to 160°C while exhibiting a temperature sensitivity of -7.3 pm/°C. The reflected power of the Bragg wavelength remains constant up to a temperature of 130°C before declining at higher temperatures with an overall reduction of 2.5 dB at 160°C. However, decreasing temperature results in a complete recovery of the peak power, facilitating steam pressure sterilization (129°C, 0.17 MPa) of the polymer planar waveguide Bragg grating.
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