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The production and use of wood-fuel pellets have increased significantly worldwide in recent years. The increased use of biomaterials has resulted in higher raw material prices, and there are no signs that indicate a decrease in raw material competition. Additives can be used for different purposes. Partly, they are used to facilitate the use of new raw materials to increase the raw material base, and partly, they are used to decrease the energy use in the pelletizing process. They are also used to increase durability or shelf life. Consequently, it is necessary to do research that systematically investigates the consequences of using additives. In this work, it is investigated how various percentages of different kinds of starch influence pellet properties, including shelf life and energy use in the pelletizing process. Four different starch grades were used: native wheat starch, oxidized corn starch, native potato starch, and oxidized potato starch. The pellets were produced in a small industrial pellet press located at Karlstad University, Karlstad, Sweden. The result shows that starch increases the durability of the pellets. Oxidized starches increase the durability more than native starches, and the best results were obtained by adding oxidized corn starch. The durability did not decrease with storage time when the pellets were stored indoors during 7 months. The oxidation process was not consistently altered by the addition of starch. The energy consumption of the pellet press decreases when starch is added. Again, the oxidized corn starch showed the best result; when 2.8% of corn starch was added, the average energy consumption was reduced by 14%.

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The mechanism of bonding in biomass pellets is such a complex event to comprehend, as the nature of the bonds formed between combining particles and their relevance to pellet quality are not completely understood. In this study, pure and blended biomass pellets made from Norway spruce and pea starch were characterized using advanced analytical instruments able to provide information beyond what is visible to the human eye, with intent to investigate differences in bonding mechanism relevant to quality. The results, which were comprehensively interpreted from a structural chemistry perspective, indicated that, at a molecular level, the major disparity in bonding mechanism between particles of the pellets and the quality of the pellets, defined in terms of strength and burning efficiency, were determined by variation in the concentration of polar functional groups emanating from the major organic and elemental components of the pellets, as well as the strength of the bonds between atoms of these groups. Microscopic-level analysis, which did not provide any clear morphological features that could be linked to incongruity in quality, showed fracture surfaces of the pellets and patterns of surface roughness, as well as the mode of interconnectivity of particles, which were evidence of the production of pellets with dissimilarities in particle bonding mechanism and visual appearance.

In order to increase the use of a variated raw material base for pellet production with a maintained density level, knowledge of the biomaterials’ ability to counteract any springback effects is essential. In this study, the springback effects were investigated for single press produced pellets from cellulose, hemicelluloses, pectin, and two woods at different moisture contents. The change in pellet coloring was also tested through a spectrophotometer for both xylan and carboxymethyl cellulose (CMC) pellets. The results show that the density of xylan pellets is much higher than glucomannan, for both green and cured pellets, and that the length of the pellets, as well as springback contribution, differ between the hemicelluloses. The study also presents results showing that both xylan and CMC pellets have a mutually identical spectrum and that the changes in the structure of xylan are not only related to moisture content, but are also pressure-related. The study also postulates that the color difference of the xylan pellets is a result of physical changes in the structure, as opposed to being of a chemical nature.