The following article is the first attempt to investigate the supramolecular structure of cellulose with the varied moisture content by the means of Fourier-transform and near infrared spectroscopy techniques. Moreover, authors aimed at the detailed and precise presentation of IR spectra interpretation approach in order to create a reliable guideline for other researchers. On the basis of obtained data, factors indicating biopolymer crystallinity and development of hydrogen interactions were calculated and the peaks representing hydrogen bonding (7500–6000 cm−1, 3700–3000 cm−1, and 1750–1550 cm−1) were resolved using the Gaussian distribution function. Then, the deconvoluted signals have been assigned to the specific interactions occurring at the supramolecular level and the hydrogen bond length, as well bonding-energy were established. Furthermore, not only was the water molecules adsorption observed, but also the possibility of the 3OH⋯O5 intramolecular hydrogen bond shortening in the wet state was found-from (27,786 ± 2) 10−5 nm to (27,770 ± 5) 10−5 nm. Additionally, it was proposed that some deconvoluted signals from the region of 3000–2750 cm−1 might be assigned to the hydroxyl group-incorporated hydrogen bonding, which is, undoubtedly, a scientific novelty as the peak was not resolved before.
Anisometric microgels are prepared via thermal crosslinking using an in-mold polymerization technique. Star-shaped poly(ethylene oxide-stat-propylene oxide) polymers, end-modified with amine and epoxy groups, form hydrogels, of which the mechanical properties and gelation rate can be adjusted by the temperature, duration of heating, and polymer concentration. Depending on the microgel stiffness, the rod-shaped microgels self-assemble into ordered or disordered structures.
The following article highlights the importance of an indispensable process in cellulose fibers (UFC100) modification which may change the biopolymer properties—drying. The reader is provided with a broad range of information considering the drying process consequences on the chemical treatment of the cellulose. This research underlines the importance of UFC100 moisture content reduction considering polymer composites application with the employment of a technique different than thermal treating. Therefore, a new hybrid chemical modification approach is introduced. It consists of two steps: solvent exchange (with ethanol either hexane) and chemical treatment (maleic anhydride—MA). With the use of Fourier-transform infrared spectroscopy (FT-IR), it has been proven that the employment of different solvents may contribute to the higher yield of the modification process as they cause rearrangements in hydrogen bonds structure, swell the biopolymer and, therefore, affect its molecular packing. Furthermore, according to the thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC), the improvement in fibers thermal resistance was noticed, e.g., shift in the value of 5% temperature mass loss from 240 °C (regular modification) to 306 °C (while solvent employed). Moreover, the research was broadened with cellulose moisture content influence on the modification process—tested fibers were either dried (D) or not dried (ND) before the hybrid chemical treatment. According to the gathered data, D cellulose exhibits elevated thermal resistance and ND fibers are more prone to the MA modification. What should be emphasized, in the case of all carried out UFC100 treatments, is that a decrease in moisture contend was evidenced—from approximately 4% in case of thermal drying to 1.7% for hybrid chemical modification. This is incredibly promising considering the possibility of the treated fibers application in polymer matrix.
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