The present article highlights an approach to generating contrasting patterns from drying colloidal droplets in a liquid bridge configuration, different from well-known coffee rings. Reduction of the confinement distance (the gap between the solid surfaces) leads to systematized nanoparticle agglomeration yielding spoke-like patterns similar to those found on scallop shells instead of circumferential edge deposition. Alteration of the confinement distance modulates the curvature that entails variations in the evaporation flux across the liquid−vapor interface. Consequently, flow inside different liquid bridges (LBs) varies significantly for different confinement distance. Small confinement distance results in the stick−slip motion of squeezed liquid bridges. On the contrary, the stretched LBs exhibit pinned contact lines. The confinement distance determines the characteristic length scales of the thin film formed near the contact line, and its theoretical estimations are validated against the experimental observations using reflection interferometry, further exhibiting good agreement (in order of magnitude). We decipher a proposition that a drying liquid thin film (height ∼ O(10 −7 )m) present during dewetting near the three-phase contact line is responsible for the aligned deposition of particles. The coupled interplay of contact line dynamics, evaporation induced advection, and dewetting of the thin film at a threephase interface contributes to the differences in deposition patterns.
We have investigated the flow and desiccation-driven self-assembly of Klebsiella Pneumoniae in the naturally evaporating sessile droplets. Klebsiella Pneumoniae exhibits extensive changes in its morphology and forms unique patterns as the droplet dries, revealing hitherto unexplored rich physics governing its survival and infection strategies. Self-assembly of bacteria at the droplet contact line is characterized by order-to-disorder packing transitions with high packing densities and excessive deformations (bacteria deforms nearly twice its original length scales). In contrast, thin-film instability-led hole formation at the center of the droplet engenders spatial packing of bacteria analogous to honeycomb weathering. The varying physical forces acting on bacteria based on their respective spatial location inside the droplet cause an assorted magnitude of physical stress. Self-assembly favors the bacteria at the rim of the droplet, leading to enhanced viability and pathogenesis on the famously known “coffee ring” of the droplet compared to the bacteria present at the center of the droplet residue. Mechanistic insights gained via our study can have far-reaching implications for bacterial infection through droplets, e.g., through open wounds.
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