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We report on reversible light-controlled conductance switching in devices consisting of multiwalled carbon nanotube (MWCNT)-polymer nanocomposites blended with azobenzene molecules and photoisomerization of the latter. Both the azobenzene molecules and MWCNT, which are functionalized with carboxyl groups (MWCNT-COOH), are embedded independently in a poly(methyl methacrylate) matrix, and thin films are prepared by using a simple spin-coating technique. We demonstrate the feasibility of the present concept with a photocurrent switching amplitude of almost 10%.

We report (95)Zr and (57)Co radiotracer diffusivities and viscosity data in the equilibrium liquid state of a bulk metallic glass forming Zr(46.75)Ti(8.25)Cu(7.5)Ni(10)Be(27.5) melt (Vitreloy 4) far above the liquidus temperature T(l) that are not affected by convection, as evidenced via quasielastic neutron scattering. Zr diffusion is strongly decoupled from diffusion of the smaller components by more than a factor of 4 at T(l), although it obeys the Stokes-Einstein equation. The results suggest that, in the present Zr-based metallic glass forming systems, diffusion and viscous flow start to develop solidlike, i.e., energy-landscape-controlled, features already in the stable liquid state more than 300 K above the mode coupling temperature T(c).

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