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An evaluation of hydrothermal liquefaction (HTL) char is investigated in this work. Morphological studies, N2 adsorption behavior, FTIR analysis, thermal behavior, and elemental composition are studied. The HTL char yield showed an increase with higher operating temperatures. It increased from 11.02% to 33% when the temperature increased from 573 K to 623 K. At lower temperatures, the residence time showed an impact on the yield, while close to the critical point, residence time became less impactful. Elemental analysis showed that both higher operating temperatures and longer residence times increased the nitrogen content of the chars from 0.32% to 0.51%. FTIR analysis suggested the char became more aromatic with the higher temperatures. The aliphatic groups present diminished drastically with the increasing temperature. Residence time did not show a significant impact as much as the temperature when considering the functional group elimination. An increase in operating temperatures and residence times produced thermally stable chars. HTL char produced at the lowest operating temperature and showed both the highest surface area and pore volume. When temperature and residence time increase, more polyaromatic char is produced due to carbonization.

This paper discusses the characteristics of Birchwood gasification using the simulated results of a Computational Fluid Dynamics (CFD) model. The CFD model is developed and validated with the experimental results obtained with the fixed bed downdraft gasifier available at the University of Agder (UIA), Norway. In this work, several parameters are examined and given importance, such as producer gas yield, syngas composition, lower heating value (LHV), and cold gas efficiency (CGE) of the syngas. The behavior of the parameters mentioned above is examined by varying the biomass particle size. The diameters of the two biomass particles are 11.5 mm and 9.18 mm. All the parameters investigate within the Equivalences Ratio (ER) range from 0.2 to 0.5. In the simulations, a variable air inflow rate is used to achieve different ER values. For the different biomass particle sizes, CO, CO 2 , CH 4 , and H 2 mass fractions of the syngas are analyzed along with syngas yield, LHV, and CGE. At an ER value of 0.35, 9.18 mm diameter particle shows average maximum values of 60% of CGE and 2.79 Nm 3 /h of syngas yield, in turn showing 3.4% and 0.09 Nm 3 /h improvement in the respective parameters over the 11.5 mm diameter biomass particle.

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