Methane-air mixtures at high fill pressures up to 30 bar and high temperatures up to 200°C were ignited in a high-pressure chamber with automated fill control by a 5 ns pulsed Nd:YAG laser at 1064 nm wavelength. Both, the minimum input laser pulse energy for ignition and the transmitted fraction of energy through the generated plasma were measured as a function of the air/fuel-equivalence ratio (λ). The lean-side ignition limit of methane-air mixtures was found to be λ=2.2. However, only λ<2.1 seems to be practically usable. As a comparison, the limit for conventional spark plug ignition of commercial natural gas engines is λ=1.8. Only with excessive efforts λ=2.0 can be spark ignited. The transmitted pulse shape through the laser-generated plasma was determined temporally as well as its dependence on input laser energy and properties of the specific gases interacting. For a first demonstration of the practical applicability of laser ignition, one cylinder of a 1 MW natural gas engine was ignited by a similar 5 ns pulsed Nd:YAG laser at 1064 nm. The engine worked successfully at λ=1.8 for a first test period of 100 hr without any interruption due to window fouling and other disturbances. Lowest values for NOx emission were achieved at λ=2.05 NOx=0.22 g/KWh. Three parameters obtained from accompanying spectroscopic measurements, namely, water absorbance, flame emission, and the gas inhomogeneity index have proven to be powerful tools to judge laser-induced ignition of methane-air mixtures. The following effects were determined by the absorption spectroscopic technique: formation of water in the vicinity of the laser spark (semi-quantitative); characterization of ignition (ignition delay, incomplete ignition, failed ignition); homogeneity of the gas phase in the vicinity of the ignition; and the progress of combustion.

Laser ignition has been discussed widely as a potentially superior ignition source for technical appliances such as internal combustion engines. Ignition strongly affects overall combustion, and its early stages in particular have strong implications on subsequent pollutant formation, flame quenching, and extinction. Our research here is devoted to the experimental investigation of the early stages of laser-induced ignition of CH4/air mixtures up to high pressures. Tests were performed in a 0.9-l combustion cell with initial pressures of up to 25 bar with stoichiometric to fuel-lean mixtures using a 5-ns 50-mJ 1064-nm Nd:YAG laser. Laserinduced fluorescence (LIF) was used to obtain two dimensionally resolved images of the OH radical distribution after the ignition event. These images were used to produce an animation of laser ignition and early flame kernel development. Schlieren photography was used to investigate the laserinduced shock wave, hot core gas, and developing flame ball. We extend existing knowledge to high-pressure regimes relevant for internal combustion engines.

Methane-air mixtures at high fill pressures up to 30 bar and high temperatures up to 200 °C were ignited in a high pressure chamber with automated fill control by a 5 ns pulsed Nd:YAG laser at 1064 nm wavelength. Both, the minimum input laser pulse energy for ignition and the transmitted fraction of energy through the generated plasma were measured as a function of the air/fuel-equivalence ratio (λ). The lean side ignition limit of methane-air mixtures was found to be λ = 2.4. However, only λ < 2.2 seems to be practically usable. As a comparison, the limit for conventional spark plug ignition of commercial natural gas engines is λ = 1.8. Only with excessive efforts λ = 2.0 can be spark-ignited. The transmitted pulse shape through the laser-generated plasma was determined temporally as well as its dependence on input laser energy and properties of the specific gases interacting. For a first demonstration of the practical applicability of laser ignition, one cylinder of a 1 MW natural gas engine was ignited by a similar 5 ns pulsed Nd:YAG laser at 1064 nm. The engine worked successfully at λ = 1.8 for a first test period of 100 hours without any interruption due to window fouling and other disturbances. Lowest values for NOx emission were achieved at λ = 2.05 (NOx = 0.22 g/KWh). Three parameters obtained from accompanying spectroscopic measurements, namely water absorbance, flame emission and the gas inhomogeneity index have proven to be a powerful tool to judge laser-induced ignition of methane-air mixtures. The following effects were determined by the absorption spectroscopic technique: formation of water in the vicinity of the laser spark (semi-quantitative); characterization of ignition (ignition delay, incomplete ignition, failed ignition); homogeneity of the gas phase in the vicinity of the ignition and the progress of combustion.

A laser-based system should be advantageous to a spark-plug based ignition system. Free choice of the ignition spot and precise timing constitute two major advantages. Multi point laser ignition could lead to higher efficiencies, and laser ignition as such is capable of igniting leaner mixtures than a spark plug, thereby decreasing thermal NOx and soot emissions. This paper is devoted to advances in optical diagnostics of laser ignition for future internal combustion engines. The focus of this paper is on diagnostics at high pressures, that is engine-like conditions. Laser ignition tests were performed with the fuels methane, hydrogen and biogas in static combustion cells with dimensions comparable to stationary engines. A Nd:YAG laser (5 ns pulse duration, wavelength 1064 nm, 1–20 mJ pulse energy) was used to ignite gaseous fuel/air mixtures at initial pressures of 1–3 MPa. Schlieren photography and laser-induced fluorescence (LIF) were used for optical diagnostics (flame kernel development, shock wave propagation). The lean burn characteristics were investigated. Schlieren photography was used to determine the velocity of the shock wave and to study the influence of the shock wave on temperature rise and energy loss. Using planar laser-induced fluorescence (PLIF), the spatial distribution of the combustion intermediates OH and formaldehyde were recorded. The temporally resolved imaging shows that the initial stages of the flame front evolution closely follows the turbulence and density fluctuations caused by the shock and pressure wave induced by the laser spark. In this paper, results from LIF spectroscopy and Schlieren photography are compared. Depending on the laser pulse energy and focus size, at later stages after the ignition the flame front propagation approaches the laminar burning regime and flame front speed decrease. Flame front break up at lean conditions indicates the limit of the ignitable mixture fraction when the speed due to spark-induced convection exceeds the flame propagation rate.

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