Producing a global and comprehensive description of atmospheric aerosols requires integration of ground-based, airborne, satellite and model datasets. Due to its complexity, aerosol monitoring requires the use of several data records with complementary information

Abstract. Desert dust aerosols are the most prominent tropospheric aerosols, playing an important role in the earth's climate. However, their radiative forcing is currently not known with sufficient precision to even determine its sign. The sources of uncertainty are multiple, one of them being a poor characterisation of the dust aerosol's vertical profile on a global scale. In this work, we tackle this scientific issue by designing a method for retrieving dust aerosol vertical profiles from Thermal Infrared measurements by Infrared Atmospheric Sounding Interferometer (IASI) instruments onboard the Metop satellite series. IASI offers almost global coverage twice a day, and long (past and future) time series of radiances, therefore being extremely well suited for climate studies. Our retrieval follows Rodger's formalism and is based on a two-step approach, treating separately the issues of low altitude sensitivity and difficult a priori definition. We compare our results for a selected test case above the Atlantic Ocean and North Africa in June 2009, with optical depth data from MODIS, aerosol absorbing index from GOME-2 and OMI, and vertical profiles of extinction coefficients from CALIOP. We also use literature information on desert dust sources to interpret our results above land. Our retrievals provide perfectly reasonable results in terms of optical depth. The retrieved vertical profiles (with on average 1.5 degrees of freedom) show most of the time sensitivity down to the lowest layer, and agree well with CALIOP extinction profiles for medium to high dust optical depth. We conclude that this new method is extremely promising for improving the scientific knowledge about the 3-D distribution of desert dust aerosols in the atmosphere.

The interactions of simple carbohydrates with aromatic moieties have been investigated experimentally by NMR spectroscopy. The analysis of the changes in the chemical shifts of the sugar proton signals induced upon addition of aromatic entities has been interpreted in terms of interaction geometries. Phenol and aromatic amino acids (phenylalanine, tyrosine, tryptophan) have been used. The observed sugar-aromatic interactions depend on the chemical nature of the sugar, and thus on the stereochemistries of the different carbon atoms, and also on the solvent. A preliminary study of the solvation state of a model monosaccharide (methyl beta-galactopyranoside) in aqueous solution, both alone and in the presence of benzene and phenol, has also been carried out by monitoring of intermolecular homonuclear solvent-sugar and aromatic-sugar NOEs. These experimental results have been compared with those obtained by density functional theory methods and molecular mechanics calculations.

Abstract. Aerosol-layer height is essential for understanding the impact of aerosols on the climate system. As part of the European Space Agency Aerosol_cci project, aerosollayer height as derived from passive thermal and solar satellite sensors measurements have been compared with aerosollayer heights estimated from CALIOP measurements. The Aerosol_cci project targeted dust-type aerosol for this study. This ensures relatively unambiguous aerosol identification by the CALIOP processing chain. Dust-layer height was estimated from thermal IASI measurements using four different algorithms (from BIRA-IASB, DLR, LMD, LISA) and from solar GOME-2 (KNMI) and SCIAMACHY (IUP) measurements. Due to differences in overpass time of the various satellites, a trajectory model was used to move the CALIOPderived dust heights in space and time to the IASI, GOME-2 and SCIAMACHY dust height pixels. It is not possible to construct a unique dust-layer height from the CALIOP data. Thus two CALIOP-derived layer heights were used: the cumulative extinction height defined as the height where the CALIOP extinction column is half of the total extinction column, and the geometric mean height, which is defined as the geometrical mean of the top and bottom heights of the dust layer. In statistical average over all IASI data there is a general tendency to a positive bias of 0.5-0.8 km against CALIOP extinction-weighted height for three of the four algorithms assessed, while the fourth algorithm has almost no bias. When comparing geometric mean height there is a shift of −0.5 km for all algorithms (getting close to zero for the three algorithms and turning negative for the fourth). The standard deviation of all algorithms is quite similar and ranges between 1.0 and 1.3 km. When looking at different conditions (day, night, land, ocean), there is more detail in variabilities (e.g. all algorithms overestimate more at night than during the day). For the solar sensors it is found that on average SCIAMACHY data are lower by −1.097 km (−0.961 km) compared to the CALIOP geometric mean (cumulative extinction) height, and GOME-2 data are lower by −1.393 km (−0.818 km).

Recent MS studies have suggested that serine clusters could have played a role in the origin of homochirality on Earth. Aqueous serine solutions have been probed in order to see if serine clusters, such as those observed by MS, are present in solution. IR measurements as well as NMR chemical shift and diffusion coefficient measurements, as a function of pH and serine concentration, suggest that these clusters do not exist in solution. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)

The lack of aerosol information over the cryosphere introduces large uncertainties to our understanding of phenomenon, known as the Arctic Amplification (AA) and its feedback mechanisms. The aerosol optical depth (AOD) describes the optical characteristics of aerosol loading. This paper describes a novel algorithm, which retrieves AOD above snow-covered regions from the measurements of the up-welling radiation at the top of atmosphere, observed by the Advanced Along-Track Scanning Radiometer (AATSR) and the Sea and Land Surface Temperature Radiometer (SLSTR) instruments. The algorithm optimizes the generic eXtensible Bremen Aerosol/cloud and surfacE parameters Retrieval (XBAER) approach for longer wavelengths over the cryosphere. The algorithm utilizes the characteristics of solar bidirectional distribution properties of snow and aerosol at wavelength 3.7 μm to derive above-snow-AOD. Since the impact of fine-mode aerosol on 3.7 μm is ignorable, the retrieved AOD in this manuscript represents mainly coarse-mode dominated part. A novel method to extract the solar reflection part at 3.7 μm is presented and used in the surface parameterization. Two aerosol types (sea saltdominated and dust-dominated) are used and the best-fit type is derived by an iterative procedure, using a Look-Up-Table (LUT) approach. Sensitivity studies of the impact on the retrieved AOD using XBAER algorithm, which investigate the impacts of aerosol type, snow surface emissivity and potential cloud contamination under typical AATSR observation conditions, are presented. The sensitivity studies show that the surface parametrization and aerosol typing are suitable for the retrieval of above-snow-AOD over the Arctic snow-covered region. AOD observations retrieved in this study from AATSR (2002-2012) observation collocated with those from the Aerosol Robotic Network (AERONET) sites over Greenland show good agreement. 72.1% of the match-ups fall into the expected error envelope of (± 0.15AOD ± 0.025). The AATSR derived above-snow-AOD at 0.55 μm research product has also been compared with Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations (CALIPSO) aerosol product, the Mineral Aerosols Profiling from Infrared Radiances (MAPIR) derived Infrared Atmospheric Sounding Interferometer (IASI) AOD research product, and the Modern-Era Retrospective analysis for Research and Applications, Version 2 (MERRA-2) AOD simulations over Greenland on April 2011. The comparison reveals that all datasets show similar patterns for the AOD above Greenland. The AOD is smaller in central Greenland and larger over the coastline regions. The XBAER derived above-snow-AOD has improved coverage, as compared to that of the existing AATSR aerosol product. The transition between above-snow-AOD and AOD derived over surrounding ocean surfaces does not indicate any systematic errors. Two aerosol transport events have been well-captured by the XBAER derived above-snow-AOD research product. The new algorithm is also applied to the SLSTR onboard Sentinel-3 demonstrating n...

Volcanic ash is emitted by most eruptions, sometimes reaching the stratosphere. In addition to its climate effect, ash may have a significant impact on civilian flights. Currently, the horizontal distribution of ash aerosols is quite extensively studied, but not its vertical profile, while of high importance for both applications mentioned. Here, we study the sensitivity of the thermal infrared spectral range to the altitude distribution of volcanic ash, based on similar work that was undertaken on mineral dust. We use measurements by the Infrared Atmospheric Sounding Interferometer (IASI) instruments onboard the MetOp satellite series. The retrieval method that we develop for the ash vertical profile is based on the optimal estimation formalism. This method is applied to study the eruption of the Chilean volcano Puyehue, which started on the 4th of June 2011. The retrieved profiles agree reasonably well with Cloud-Aerosol LiDAR with Orthogonal Polarization (CALIOP) measurements, and our results generally agree with literature studies of the same eruption. The retrieval strategy presented here therefore is very promising for improving our knowledge of the vertical distribution of volcanic ash and obtaining a global 3D ash distribution twice a day. Future improvements of our retrieval strategy are also discussed.

The Mineral Aerosol Profiling from Infrared Radiances (MAPIR) algorithm retrieves vertical dust concentration profiles from cloud-free Infrared Atmospheric Sounding Interferometer (IASI) thermal infrared (TIR) radiances using Rodgers' optimal estimation method (OEM). We describe the new version 4.1 and evaluation results. Main differences with respect to previous versions are the Levenberg-Marquardt modification of the OEM, the use of the logarithm of the concentration in the retrieval and the use of Radiative Transfer for TOVS (RTTOV) for in-line radiative transfer calculations. The dust aerosol concentrations are retrieved in seven 1 km thick layers centered at 0.5 to 6.5 km. A global data set of the daily dust distribution was generated with MAPIR v4.