In this work, we studied the application of photovoltaic solar energy for driving the electrochemical processes of electrocoagulation and electrooxidation to remediate drilling fluid wastewater, and simultaneously harvest energy in the form of electrolytic hydrogen gas produced at the cathode. The electrocoagulation was performed with sacrificial aluminium electrodes and electrooxidation with dimensionally stable boron-doped diamond electrodes in batch-wise and continuously operated mode, and their efficiency in both pollutants removal and hydrogen gas production was elucidated. The parameters affecting the efficiency of the applied electrochemical processes, such as applied current density, pH, electroprocessing time and flow rate, were investigated. The electrochemical processing was monitored by measuring the chemical oxygen demand (COD) of treated wastewater. The electrocoagulation treatment conducted with current densities of 30, 60 and 90 mA/cm2 reduced the wastewater COD by about 67%, whereas the electrooxidation treatment at the same conditions yielded a COD removal of over 95%. The amount of produced hydrogen was 171 L/g COD removed from treated wastewater.
Biodiesel is a reliable and promising replacement of fossil diesel. It is stable, less toxic and can be produced from sustainable resources, including a variety of raw materials. Currently, the most widely used are vegetable oils (edible and nonedible), due to their availability. The present paper considers the potential of obtaining fatty acid ethyl esters (FAEE) from corn oil, which is a byproduct of bioethanol production process. The ultimate outcome would definitely increase the profitability of the initial bioethanol production process. The biodiesel production process was implemented in two steps, due to the high content of free fatty acids of the obtained corn oil. The first step includes an acid-catalyzed esterification process and the second step comprises an alkali-catalyzed transesterification process to receive FAEE. Two different catalysts (sulfuric acid and p-toluene sulfonic acid) were utilized and compared each other in the esterification process, in order to cope with high acid number of the raw material. A comprehensive qualitative and quantitative analysis of both feedstock and biodiesel was performed using gas chromatography-mass spectrometry method. The obtained biodiesel was characterized by a significantly lower cloud point compared to the feedstock and high acid number.
The oil and gas industry is definitely considered the main contributor in the energy sector, acting as the lifeblood of our planet. However, environmental contamination by crude oil and petroleum products due to anthropogenic activities is of great concern. Nestos River springs from Bulgaria and has a total length of 234 km, from which 135 km belong on Greek land. It is globally recognized as nature’s miracle accommodating a variety of habitats, flora, and fauna species at the deltaic area protected by the RAMSAR Convention. In the current study, water and sediment samples from three different sites along the river course and other six sites of the delta region and the surrounding sea area were selected in order to investigate the potential environmental impact of the nearby oil and gas industry in the Prinos-Kavala basin that operates over 40 years. The samples were analyzed by fingerprinting techniques using gas chromatography-mass spectrometry. Crude oil samples and different petroleum products were also analyzed to disclose specific markers (biomarkers) that characterize the different sources of oil spills. The analytical data revealed that the distribution of biomarkers is a valuable tool in oil spill identification as well as in their correlation to suspected sources. Extract ion chromatograms of the reference samples showed significant differences in the distribution of n-alkane, isoprenoid, sterane, triterpane, and dibenzothiophene compounds. The results on the analyzed water and sediment samples bared no evidence of environmental hazards associated with the hydrocarbon exploration and production activities of the neighboring oil and gas company.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
hi@scite.ai
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
Copyright © 2024 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.