Non-classical behaviour, brought about by a confinement that imposes spatial constraints on molecules, is opening avenues to novel applications. For example, carbon nanotubes, which show rapid and selective transport of small molecules across the nanotubes, have significant potential as biological or chemical separation materials for organic solvents or gaseous molecules. With polymers, when the dimensions of a confining volume are much less than the radius of gyration, a quantitative understanding of perturbations to chain dynamics due to geometric constraints remains a challenge and, with the development of nanofabrication processes, the dynamics of confined polymers have significant technological implications. Here, we describe a weak molecular-weight-dependent mobility of polymers confined within nanoscopic cylindrical pores having diameters smaller than the dimension of the chains in the bulk. On the basis of the chain configuration along the pore axis, the measured mobility of polymers in the confined geometry is much higher than the mobility of the unconfined chain. With the emergence of nanofabrication processes based on polymer flow, the unexpected enhancement in flow and reduction in intermolecular entanglements are of significant importance in the design and execution of processing strategies.
High density nanoporous patterns were imprinted on bulk ZnO single‐crystal substrates. The nanostamps were prepared via replication from nanoporous anodized alumina. Using the nanoimprinting technique, nanopatterns were successfully transferred onto the ZnO surface. Here we demonstrate that the light emitting efficiency of ZnO is highly enhanced through the simple nano‐texturing. This simple method is applicable to any other light emitting diodes where the antireflective surface coating is desirable. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)
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