We investigate an excitonic peak appearing in low-temperature photoluminescence of monolayer transition metal dichalcogenides (TMDCs), which is commonly associated with defects and disorder. First, to uncover the intrinsic origin of defect-related excitons, we study their dependence on gate voltage, excitation power, and temperature in a prototypical TMDC monolayer, MoS2. We show that the entire range of behaviors of defect-related excitons can be understood in terms of a simple model, where neutral excitons are bound to ionized donor levels, likely related to sulphur vacancies, with a density of 7×10 11 cm -2 . Second, to study the extrinsic origin of defect-related excitons, we controllably deposit oxygen molecules in-situ onto the surface of MoS2 kept at cryogenic temperature. We find that in addition to trivial pdoping of 3×10 12 cm -2 , oxygen affects the formation of defect-related excitons by functionalizing the vacancy. Combined, our results uncover the origin of defect-related excitons, suggest a simple and conclusive approach to track the functionalization of TMDCs, benchmark device quality, and pave the way towards exciton engineering in hybrid organicinorganic TMDC devices.

Topological on-chip photonics based on tailored photonic crystals (PhCs) that emulate quantum valley-Hall effects has recently gained widespread interest owing to its promise of robust unidirectional transport of classical and quantum information. We present a direct quantitative evaluation of topological photonic edge eigenstates and their transport properties in the telecom wavelength range using phase-resolved near-field optical microscopy. Experimentally visualizing the detailed sub-wavelength structure of these modes propagating along the interface between two topologically non-trivial mirror-symmetric lattices allows us to map their dispersion relation and differentiate between the contributions of several higher-order Bloch harmonics. Selective probing of forward- and backward-propagating modes as defined by their phase velocities enables direct quantification of topological robustness. Studying near-field propagation in controlled defects allows us to extract upper limits of topological protection in on-chip photonic systems in comparison with conventional PhC waveguides. We find that protected edge states are two orders of magnitude more robust than modes of conventional PhC waveguides. This direct experimental quantification of topological robustness comprises a crucial step toward the application of topologically protected guiding in integrated photonics, allowing for unprecedented error-free photonic quantum networks.

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Molecules intercalating two-dimensional (2D) materials form complex structures that have been mostly characterized by spatially averaged techniques. Here we use aberration-corrected scanning transmission electron microscopy and densityfunctional-theory (DFT) calculations to study the atomic structure of bilayer graphene (BLG) and few-layer graphene (FLG) intercalated with FeCl3. In BLG we discover two distinct intercalated structures that we identify as monolayer-FeCl3 and monolayer-FeCl2. The two structures are separated by atomically sharp boundaries and induce large but different free-carrier densities in the graphene layers, 7.1 × 10 cm -2 and 7.8 × 10 cm -2 respectively. In FLG, we observe multiple FeCl3 layers stacked in a variety of possible configurations with respect to one another. Finally, we find that the microscope's electron beam can convert the FeCl3 monolayer into FeOCl monolayers in a rectangular lattice. These results reveal the need for a combination of atomically-resolved microscopy, spectroscopy, and DFT calculations to identify intercalated structures and study their properties.

The introduction of topological concepts to the design of photonic crystal cavities holds great promise for applications in integrated photonics due to the prospect of topological protection. This study examines the signatures of topological light confinement in the leakage radiation of 2D topological photonic crystal cavities. The cavities are implemented in an all-dielectric platform that features the photonic quantum spin Hall effect at telecom wavelengths and supports helical edge states that are weakly coupled to the radiation continuum. The modes of resonators scaling down to single point defects in the surrounding bulk lattice are characterized via spectral position and multipolar nature of the eigenstates. The mode profiles in real and momentum space are mapped using far-field imaging and Fourier-spectropolarimetry, revealing how certain properties of the cavity modes reflect on their origin in the topological bandstructure. This includes band-inversion-induced confinement and inverted scaling of mode spectra for trivial and topological defect cavities. Furthermore, hallmarks of topological protection in the loss rates are demonstrated, which are largely unaffected by cavity shape and size. The results constitute an important step toward the use of radiative topological cavities for on-chip confinement of light, control of emitted wave fronts, and enhancement of light-matter interactions.