The estimated D 13 C ant and DC ant and their relationship to each other and to water mass distribution suggest that the Polar Water entering the Nordic seas from the north is undersaturated with respect to the present atmospheric anthropogenic CO 2 levels and promotes a local uptake of C ant within the Nordic seas. In contrast, the Atlantic Water entering from the south appears equilibrated. It carries with it anthropogenic carbon which will be sequestered at depth as the water overturns. This preequilibration leaves no room for further uptake of C ant in the parts of the Nordic seas dominated by Atlantic Water. The upper ocean pCO 2 in these regions appears to have increased at a greater rate than the atmospheric pCO 2 over the last 2 decades; this is reconcilable with a large lateral advective supply of C ant .Citation: Olsen, A., et al. (2006), Magnitude and origin of the anthropogenic CO 2 increase and 13 C Suess effect in the Nordic seas since 1981, Global Biogeochem. Cycles, 20, GB3027,
Recent studies based on ocean and atmospheric carbon dioxide (CO2) observations, suggesting that the ocean carbon uptake has been reduced, may help explain the increase in the fraction of anthropogenic CO2 emissions that remain in the atmosphere. Is it a response to climate change or a signal of ocean natural variability or both? Regional process analyses are needed to follow the ocean carbon uptake and to enable better attributions of the observed changes. Here, we describe the evolution of the surface ocean CO2 fugacity (fCO2oc) over the period 1993–2008 in the North Atlantic subpolar gyre (NASPG). This analysis is based primarily on observations of dissolved inorganic carbon (DIC) and total alkalinity (TA) conducted at different seasons in the NASPG between Iceland and Canada. The fCO2oc trends based on DIC and TA data are also compared with direct fCO2 measurements obtained between 2003 and 2007 in the same region. During winters 1993–2003, the fCO2oc growth rate was 3.7 (±0.6) μatm yr−1, higher than in the atmosphere, 1.8 (±0.1) μatm yr−1. This translates to a reduction of the ocean carbon uptake primarily explained by sea surface warming, up to 0.24 (±0.04) °C yr−1. This warming is a consequence of advection of warm water northward from the North Atlantic into the Irminger basin, which occurred as the North Atlantic Oscillation (NAO) index moved into a negative phase in winter 1995/1996. In winter 2001–2008, the fCO2oc rise was particularly fast, between 5.8 (±1.1) and 7.2 (±1.3) μatm yr−1 depending on the region, more than twice the atmospheric growth rate of 2.1 (±0.2) μatm yr−1, and in the winter of 2007–2008 the area was supersaturated with CO2. As opposed to the 1990s, this appears to be almost entirely due to changes in seawater carbonate chemistry, the combination of increasing DIC and decreasing of TA. The rapid fCO2oc increase was not only driven by regional uptake of anthropogenic CO2 but was also likely controlled by a recent increase in convective processes‐vertical mixing in the NASPG and cannot be directly associated with NAO variability. The fCO2oc increase observed in 2001–2008 leads to a significant drop in pH of −0.069 (±0.007) decade−1.
Abstract. Ship-based time series, some now approaching over 3 decades long, are critical climate records that have dramatically improved our ability to characterize natural and anthropogenic drivers of ocean carbon dioxide (CO2) uptake and biogeochemical processes. Advancements in autonomous marine carbon sensors and technologies over the last 2 decades have led to the expansion of observations at fixed time series sites, thereby improving the capability of characterizing sub-seasonal variability in the ocean. Here, we present a data product of 40 individual autonomous moored surface ocean pCO2 (partial pressure of CO2) time series established between 2004 and 2013, 17 also include autonomous pH measurements. These time series characterize a wide range of surface ocean carbonate conditions in different oceanic (17 sites), coastal (13 sites), and coral reef (10 sites) regimes. A time of trend emergence (ToE) methodology applied to the time series that exhibit well-constrained daily to interannual variability and an estimate of decadal variability indicates that the length of sustained observations necessary to detect statistically significant anthropogenic trends varies by marine environment. The ToE estimates for seawater pCO2 and pH range from 8 to 15 years at the open ocean sites, 16 to 41 years at the coastal sites, and 9 to 22 years at the coral reef sites. Only two open ocean pCO2 time series, Woods Hole Oceanographic Institution Hawaii Ocean Time-series Station (WHOTS) in the subtropical North Pacific and Stratus in the South Pacific gyre, have been deployed longer than the estimated trend detection time and, for these, deseasoned monthly means show estimated anthropogenic trends of 1.9±0.3 and 1.6±0.3 µatm yr−1, respectively. In the future, it is possible that updates to this product will allow for the estimation of anthropogenic trends at more sites; however, the product currently provides a valuable tool in an accessible format for evaluating climatology and natural variability of surface ocean carbonate chemistry in a variety of regions. Data are available at https://doi.org/10.7289/V5DB8043 and https://www.nodc.noaa.gov/ocads/oceans/Moorings/ndp097.html (Sutton et al., 2018).
Abstract. The Iceland Sea is one part of the Nordic Seas. Cold Arctic Water prevails there and the deep-water is an important source of North Atlantic Deep Water. We have evaluated time series observations of measured pCO 2 and total CO 2 concentration from discrete seawater samples during 1985-2008 for the surface and 1994-2008 for deep-water, and following changes in response to increasing atmospheric carbon dioxide. The surface pH in winter decreases at a rate of 0.0024 yr −1 , which is 50% faster than average yearly rates at two subtropical time series stations, BATS and ESTOC. In the deep-water regime (>1500 m), the rate of pH decline is a quarter of that observed in surface waters. The surface seawater carbonate saturation states ( ) are about 1.5 for aragonite and 2.5 for calcite, about half of levels found in subtropical surface waters. During 1985During -2008, the degree of saturation ( ) decreased at an average rate of 0.0072 yr −1 for aragonite and 0.012 yr −1 for calcite. The aragonite saturation horizon is currently at 1710 m and shoaling at 4 m yr −1 . Based on this rate of shoaling and on the local hypsography, each year another 800 km 2 of seafloor becomes exposed to waters that have become undersaturated with respect to aragonite.
Abstract. One of the major challenges to assessing the impact of ocean acidification on marine life is detecting and interpreting long-term change in the context of natural variability. This study addresses this need through a global synthesis of monthly pH and aragonite saturation state ( arag ) climatologies for 12 open ocean, coastal, and coral reef locations using 3-hourly moored observations of surface seawater partial pressure of CO 2 and pH collected together since as early as 2010. Mooring observations suggest open ocean subtropical and subarctic sites experience present-day surface pH and arag conditions outside the bounds of preindustrial variability throughout most, if not all, of the year. In general, coastal mooring sites experience more natural variability and thus, more overlap with preindustrial conditions; however, present-day arag conditions surpass biologically relevant thresholds associated with ocean acidification impacts on Mytilus californianus ( arag < 1.8) and Crassostrea gigas ( arag < 2.0) larvae in the California Current Ecosystem (CCE) and Mya arenaria larvae in the Gulf of Maine ( arag < 1.6). At the most variable mooring locations in coastal systems of the CCE, subseasonal conditions approached arag = 1. Global and regional models and data syntheses of ship-based observations tended to underestimate seasonal variability compared to mooring observations. Efforts such as this to characterize all patterns of pH and arag variability and change at key locations are fundamental to assessing present-day biological impacts of ocean acidification, further improving experimental design to interrogate organism response under real-world conditions, and improving predictive models and vulnerability assessments seeking to quantify the broader impacts of ocean acidification.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
hi@scite.ai
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
Copyright © 2024 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.