Excellent mechanical, thermal, and electrical properties of carbon nanotubes (CNTs) and nanofibers (CNFs) have motivated the development of advanced nanocomposites with outstanding and multifunctional properties. After achieving a considerable success in utilizing these unique materials in various polymeric matrices, recently tremendous interest is also being noticed on developing CNT and CNF reinforced cement-based composites. However, the problems related to nanomaterial dispersion also exist in case of cementitious composites, impairing successful transfer of nanomaterials' properties into the composites. Performance of cementitious composites also depends on their microstructure which is again strongly influenced by the presence of nanomaterials. In this context, the present paper reports a critical review of recent literature on the various strategies for dispersing CNTs and CNFs within cementitious matrices and the microstructure and mechanical properties of resulting nanocomposites.
Carbon nanotubes are the major component of nanotechnology and a considerable area of research, due to their outstanding physical and mechanical properties. Since their discovery in 1991, extensive research has been carried out to understand and exploit these unique properties in the form of composites for various applications. But the main challenge lies in transferring the properties of carbon nanotubes to the nanocomposites successfully. In this paper, recent research in the field of carbon nanotubes reinforced epoxy composites and carbon epoxy three phase composites are reviewed.
Background
The Cholera-Hospital-Based-Intervention-for-7-Days (CHoBI7) is a handwashing with soap and water treatment intervention program delivered by a health promoter bedside in a health facility and through home visits to diarrhea patients and their household members during the 7 days after admission to a health facility. In a randomized controlled trial among cholera patient households in Bangladesh, the 7-day CHoBI7 program resulted in a significant reduction in cholera among household members of cholera patients and sustained improvements in drinking water quality and handwashing with soap practices 12 months post-intervention. In an effort to take this intervention to scale across Bangladesh in partnership with the Bangladesh Ministry of Health and Family Welfare, this study evaluates the feasibility and acceptability of mobile health (mHealth) programs as a low-cost, scalable approach for CHoBI7 program delivery.
Methods
Formative research for the development of the CHoBI7 mHealth intervention included 40 semi-structured interviews, 4 mHealth workshops, 2 group discussions, and a pilot study of 52 households to assess the feasibility and acceptability of the developed mHealth program. Thematic analysis of the interviews and group discussions was conducted by two individuals separately based on emergent themes, and then themes were compared and discussed.
Results
A theory- and evidence-based approach using qualitative research methods was implemented to design the CHoBI7 mHealth program. Semi-structured interviews with government stakeholders identified perceptions and preferences for scaling the CHoBI7 mHealth program. Group discussions and semi-structured interviews with diarrhea patients and their family members identified beneficiary perceptions of mHealth and preferences for CHoBI7 mHealth program delivery. mHealth workshops were conducted as an interactive approach to draft and refine mobile message content based on stakeholder preferences. The pilot findings indicate that the CHoBI7 mHealth program has high user acceptability and is feasible to deliver to diarrhea patients that present at health facilities for treatment in Bangladesh. Both text and voice messages were recommended for program delivery. Dr. Chobi, the sender of mHealth messages, was viewed as a credible source of information that could be shared with others.
Conclusion
This study presents a theory- and evidence-based approach that can be implemented for the development of future water, sanitation, and hygiene mHealth programs in low-resource settings.
Electronic supplementary material
The online version of this article (10.1186/s12889-019-7144-z) contains supplementary material, which is available to authorized users.
This paper reports a novel approach of preparing aqueous suspensions of microcrystalline cellulose (MCC) for fabrication of cementitious composites. MCC was dispersed homogeneously in water using Pluronic F-127 as a surfactant with the help of ultrasonication process and the aqueous suspensions were added to cement/sand mixture to prepare cementitious composites. A commonly used stabilizing agent for MCC, carboxy methyl cellulose (CMC) was also used for the comparison purpose. The prepared suspensions were characterized through visual inspection, UV-Vis spectroscopy and optical microscopy. The developed composites were characterized for their bulk density, flexural and compressive properties as well as microstructure. The influence of Pluronic and CMC concentration, superplasticizer, dispersion technique and dispersion temperature on mortar's mechanical performance was thoroughly studied to find out the optimum conditions. Overall, Pluronic (with Pluronic: MCC ratio of 1:5) led to better MCC dispersion as well as dispersion stability as compared to CMC. The best mechanical performance was achieved with Pluronic in combination with superplasticizer using ultrasonication process, resulting in improvement of 106%, 31% and 66% in flexural modulus, flexural strength and compressive strengths, respectively (highest values reported till date). The bulk density and hydration of cementitious composites also improved significantly with the addition of MCC.
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