A modified nanofluid model for homogeneous–heterogeneous reactions in a gravity-driven liquid film is proposed based on the assumptions of the homogeneous reaction governed by isothermal cubic autocatalytic kinetics and the heterogeneous reaction given by first-order kinetics. The Buongiorno model is introduced to describe behaviors of nanofluids with the Boussinesq approximation being used for simplification of the buoyancy term. Multiple solutions are captured, whose stabilities are checked and discussed based on the theory of Sturm–Liouville. The influence of various physical parameters on important physical quantities is presented for different cases, including buoyancy assisting, no buoyancy, and buoyancy opposing. Different from previous studies on chemical reactions in which reactants are presumed in nanometer scale, we assume that the chemical species are of regular size, which react with each other in a nanofluid. This configuration makes our model physically more realistic than previous ones.
Abstract. An immobilized TiO2 photocatalyst with a high specific surface area was prepared on stainless steel woven meshes in order to be used packed in layers for water purification. Immobilization of such a complex shape needs a special coating technique. For this purpose, dip coating and electrophoretic deposition (EPD) techniques were used. The EPD technique gave the TiO2 coating films a better homogeneity and adhesion, fewer cracks, and a higher ·OH formation than the dip coating technique. The woven mesh structure packed in layers guaranteed an efficient light-penetration in water treatment reactor. A simple equation model was used to describe the distribution of light through the mesh layers in the presence of absorbing medium (e.g., colored water with humic acids). Maximum three or four coated meshes were enough to harvest the solar UV light from 300 nm to 400 nm with a high penetration efficiency. The separation distance between the mesh layers played an important role in the efficiency of solar light penetration through the coated mesh layers, especially in case of colored water contaminated with high concentrations of humic acid.
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