Isolating and identifying the conformational forms of molecules are imperative processes to investigate the chemical reaction pathways of individual conformers.

Piperidine has received attention in pharmaceutical synthesis and biochemical degradations because of its conformational activity. We explored the conformational structures of piperidine in the neutral (S0) and cationic (D0) ground...

Morpholine, a heterocycle composed of an ether and amine, is commonly used as a precursor in many organic synthesis processes because of the nucleophilicity induced by the lone-pair electrons of...

Demands on nontoxic nanomaterials in the short-wavelength infrared (SWIR) have rapidly grown over the past decade. Here, we present the nonstoichiometric silver chalcogenide nanocrystals of Ag x Te (x > 2) and Ag 2 Te/Ag 2 S CQDs with a tunable bandgap across the SWIR region. When the atomic percent of the metal and chalcogenide elements are varied, the emission frequency of the excitonic peak is successfully extended to 2.7 μm. Surprisingly, the Ag x Te CQD film responds to the SWIR light with a responsivity of 2.1 A/W at 78 K. Also, the Ag 2 S shell growth over the Ag 2 Te core enhances not only the emission intensity but also the structural rigidity, preventing crystal morphology deformation under the electron beam. The origin of the enhancement in the emission intensity and air stability of Ag x Te and Ag 2 Te/Ag 2 S CQDs is carefully investigated by X-ray photoelectron spectroscopy (XPS). The optical properties and infrared photocurrent of Ag x Te CQDs will provide new opportunities for solution-based SWIR applications.

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