A set of organic–rich shales of the Upper Permian Longtan Formation, which is widely developed in the northeastern part of the Sichuan Basin, is a key formation for the next step of exploration and development. At present, most studies on this set of formations have focused on the reservoir characteristics and reservoir formation mechanism of the shales, and basic studies on the palaeoenvironment and organic matter (OM) enrichment mechanism have not been fully carried out. In this paper, we recovered the sedimentary palaeoenvironment by mineralogical, elemental geochemical and organic geochemical analyses, and explored the enrichment mechanism of OM under the constraints of palaeoenvironmental evolution. The shales can be divided into two stages of sedimentary evolution: compared with the shales of the Lower Longtan Formation, the shales of the Upper Longtan Formation are relatively rich in quartz, poor in clay and carbonate minerals, and the OM type changes from type III to type II2. The depositional environment has undergone a change from sea level rise, from warm and wet climate to dry and cold climate, and from oxygen–poor condition restricted to open reduction environment; the land source input has decreased, the siliceous mineral content has increased, the biological productivity has improved, and the deposition rate has changed from high to low. A depositional model was established for the shales of the Longtan Formation, reflecting the differential reservoir formation pattern of organic matter. For the Lower Longtan Formation shales, the most important factors controlling OM content are terrestrial source input and deposition rate, followed by paleoclimate and paleo‐oxygen conditions. For the Upper Longtan Formation shales, the most important controlling factor is paleoproductivity, followed by sedimentation rate. The depositional model constructed for the Upper and Lower Longtan Formation shales can reproduce the enrichment of organic matter and provide a basis for later exploration and development.
Pore and its structural characteristics are key parameters affecting shale gas reservoir development. Accurate quantitative characterization of shale pore and its structural characteristics is of great significance for evaluating shale reservoir state. In this study, 15 shallow marine shale samples were collected in Well Y108. X-ray diffraction results indicate that brittle minerals are the most common components in shale. In this paper, various pore types are classified and characterized by scanning electron microscope images. The total porosity of shale measured by the mercury intrusion method is between 3.2% and 6.5%. In addition, a petrophysical model is established to calculate matrix porosity and fracture. The results of this model are consistent with the measured porosity. Three key parameters (VTOC > VBri > VClay) were obtained. The low-pressure N2/CO2 adsorption experiment allows for the analysis of pore volume, specific surface area, and pore size. Finally, it was determined that the primary pore types and primary shale gas reservoir space in shallow marine shale are mesopores and micropores. The impact of shale constituents on pores and their structural properties is also covered in this work. The results indicate that the enrichment of total organic carbon and brittle minerals is conducive to the development of shallow marine shale pore-fracture system. Additionally, there is a positive linear relationship between matrix porosity, pore volume, specific surface area, average pore diameter, and surface porosity.
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