Land-based enhanced rock weathering (ERW) is a biogeochemical carbon dioxide removal (CDR) strategy aiming to accelerate natural geological processes of carbon sequestration through application of crushed silicate rocks, such as basalt, to croplands and forested landscapes. However, the efficacy of the approach when undertaken with basalt, and its potential co-benefits for agriculture, require experimental and field evaluation. Here we report that amending a UK clay-loam agricultural soil with a high loading (10 kg/m 2 ) of relatively coarse-grained crushed basalt significantly increased the yield (21 ± 9.4%, SE) of the important C 4 cereal Sorghum bicolor under controlled environmental conditions, without accumulation of potentially toxic trace elements in the seeds. Yield increases resulted from the basalt treatment after 120 days without P-and K-fertilizer addition. Shoot silicon concentrations also increased significantly (26 ± 5.4%, SE), with potential benefits for crop resistance to biotic and abiotic stress.Elemental budgets indicate substantial release of base cations important for inorganic carbon removal and their accumulation mainly in the soil exchangeable pools.Geochemical reactive transport modelling, constrained by elemental budgets, indicated CO 2 sequestration rates of 2-4 t CO 2 /ha, 1-5 years after a single application of basaltic rock dust, including via newly formed soil carbonate minerals whose longterm fate requires assessment through field trials. This represents an approximately fourfold increase in carbon capture compared to control plant-soil systems without basalt. Our results build support for ERW deployment as a CDR technique compatible with spreading basalt powder on acidic loamy soils common across millions of hectares of western European and North American agriculture. K E Y W O R D Scarbon removal, crop productivity, mineral weathering, negative emissions technology, reactive transport modelling, silicon, soil acidification KELLAND Et AL. | 3659

13The Lower Mississippian (Tournaisian) Ballagan Formation in SE Scotland yields tetrapod 14 fossils that provide fresh insights into the critical period when these animals first moved onto 15 land.

A B S T R AC T : Understanding the composition of clay-rich sediments and their transportation into proximal marine basins allows us to better decipher hydroclimatic changes before and within the Palaeocene-Eocene Thermal Maximum (PETM). Only a limited number of such studies exists from the North Sea Basin, which was proximal to the volcanic activity and early rifting hypothesized to have triggered the PETM. The present study examines core material from well 22/10a-4, UK North Sea, as it exhibits an exceptionally expanded and almost stratigraphically complete fine-grained sedimentary sequence suitable for high-resolution analysis.Quantitative Newmod-for-Windows™-modelled clay mineral assemblages, rather than traditional semi-quantitative estimates, are dominated by smectite-rich, interlayered illite-smectite that probably developed from volcanogenic deposits on continental landmasses. Soil development before the PETM is consistent with the existence of a seasonal tropical climate with a prolonged dry season. A striking rise and fall of kaolinite content within the PETM onset, prior to the principal carbon-isotope excursion, is reported here. This variation is interpreted as a signal of an enhanced hydrologic cycle producing an increase in erosionally derived kaolinite, followed by a dampening of this detrital source as sea-levels rose. Global variations in PETM kaolinite concentrations are consistent with a latitudinal shift in patterns of precipitation in models of global warming.

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The occurrence of substantial quantities of black carbon (BC) in urban soil due to local dispersal following incomplete combustion of fossil fuel complicates the determination of labile soil organic carbon (SOC). Estimates of SOC content were made from loss on ignition (LOI) analyses undertaken on samples (0-15 cm depth) from comprehensive soil geochemical surveys of three UK urban areas. We randomly selected 10 samples from each decile of the LOI distribution for each of the surveys of Coventry (n = 808), Stoke-on-Trent (n = 737) and Glasgow (n = 1382) to investigate the proportions of labile SOC and BC. We determined their total organic carbon (TOC) and BC contents, and by difference the labile SOC content, and investigated the linear relationship of the latter with SOC estimates based on LOI analyses. There was no evidence for a difference in the slope of the regression for the three urban areas. We then used a linear regression of labile SOC based on LOI analyses (r 2 = 0.81) to predict labile SOC for all survey samples from the three urban areas. We attribute the significantly higher median BC concentrations in Glasgow (1.77%, compared with 0.46 and 0.59% in Coventry and Stoke-on-Trent) to greater dispersal of coal ash across the former. An analysis of the 30 samples showed that LOI at 450°C accounts for a consistent proportion of BC in each sample (r 2 = 0.97). Differences between TOC (combustion at 1050°C after removal of inorganic carbon) and an LOI estimate of SOC may be a cost-effective method for estimation of BC. Previous approaches to estimation of urban SOC contents based on half the mean SOC content of the equivalent associations under pasture, underestimate the empirical mean value.

We present a revised lithostratigraphy for the Voltaian Supergroup of Ghana, based on a review of existing literature, interpretations of remotely sensed data and reconnaissance field survey of the Volta Basin. These strata thicken eastwards, to a maximum of between 5 and 6 km adjacent to the PanAfrican Dahomeyide orogen. They began to accumulate some time after about 1000 Ma, along the margin of an epicontinental sea. Initial sedimentation, comprising the age-equivalent Kwahu and Bombouaka Groups, shows a cyclical mode of deposition controlled by eustatic changes in sea-level that produced a range of nearshore marine, littoral and terrestrial environments. A major erosional interval was followed by deposition of the 3-4 km thick Oti-Pendjari Group. Basal tillites and associated sandy diamictons are correlated with the Marinoan (end-Cryogenian) glaciation, indicating a maximum depositional age of about 635 Ma. The overlying cap carbonates and tuffs were deposited within a shallow epeiric sea bordered by a volcanically active rift system. The main part of the group records the transition from a rifted passive margin to a fully developed foreland basin receiving marine flysch in the form of argillaceous strata interbedded with highly immature wacke-type sandstones and conglomerates. Maximum accommodation space was developed within a foredeep adjacent to the Dahomeyide belt. Towards the end of the orogenic phase, the foredeep succession became partially inverted and then was buried under coarse terrestrial, red-bed molasse of the Obosum Group

The Initial Eocene Thermal Maximum (IETM) at c. 55 Ma represents a period of rapid global warming that lasted less than 200 ka. The response of vegetation to such an event, and particularly warmadapted highly diverse vegetation types, is poorly understood. Using pollen floral, clay mineral and stable carbon isotope analyses of sediments from the upper Tuscahoma Formation on the eastern US Gulf Coast (eastern Mississippi and western Alabama), we document paratropical floral changes across the PalaeoceneEocene boundary from the Wahalak #2 and lower Harrell cores. Data indicate strong changes in the abundance of kaolinite that correlate with changes in relative abundance of native pollen taxa. There is no evidence for a transient, extra-tropical flora on the US Gulf Coast that may characterize the IETM. Immigration and extinction are not associated with this event. Instead, Early Eocene plant immigration occurs in pulses and therefore is not associated directly with climate change during the IETM. The two cores share the same regional species pool but compositional differences are stronger between cores than they are either through changes in environment, increased soil erosion or chemical weathering, or through the introduction of nonnative plants. Our data suggest that vegetation change across the Palaeocene-Eocene boundary is not a single event but rather a sequence of cascading events.

The Wildmoor Sandstone Formation, proved in three boreholes drilled at Birmingham University, is dominated by fine- to medium-grained sandstones deposited in a braided river environment, within which channel lag, channel fill and abandoned channel facies are recognized. Minor proportions of aeolian sandsheet are present, as are dolocretes, not previously reported in the formation.The sandstones are feldspathic and lithic arenites, and typically are clay-poor. Early dolomite dominates the diagenetic overprint, and is preferentially developed in channellag deposits. Burial diagenetic effects are minor. Late calcite occurs as a pore-filling phase and within fractures.Minor fractures and granulation seams are oriented parallel to the NE-SW Birmingham Fault. ‘Conventional’ granulation seams, with comminution of detrital material, and more complex seams containing comminuted dolomite cement with a millimetre-wide halo of dolomite cement are present, the latter implying that the sandstone was dolomitecemented at the time of fracturing.Several scales of heterogeneity will affect groundwater solute transport. The palaeosols and abandoned channel mudstones may act as barriers to vertical flow at the decimetre scale. Dolomite-cemented channel-lag deposits may act similarly at smaller scales. Granulation seams have permeabilities of two-three orders of magnitude lower than their host sandstones, but their limited occurrence may limit their impact on larger scale flow. Matrix permeability is controlled by grain size and dolomite cement.The fines in the fine-grained, ripple cross-laminatied sandstones were extensively washed out during coring, and this lithology may be a source of sand yields in some sandstone boreholes. Although no enhancement of particle yields was seen during packer testing, the possibility remains that more comprehensive failure may occur at higher pumping rates.